RT Journal Article
T1 Evaluation of supercritical fluid chromatography accurate mass spectrometry for neonicotinoid compounds determination in wine samples
A1 Pérez Mayán, Leticia
A1 Cobo Golpe, María
A1 Ramil Criado, María
A1 Cela Torrijos, Rafael
A1 Rodríguez Pereiro, Isaac
K1 Neonicotinoids
K1 Supercritical fluid chromatography
K1 Wine analysis
K1 Accurate mass spectrometry
AB The suitability of supercritical fluid chromatography, coupled to accurate mass spectrometry (SFC-MS), for the determination of seven commercial neonicotinoid pesticides and one transformation product in wine samples has been investigated. Thorough optimization of the different parameters (column, modifier, back-flush pressure, make up, etc.) affecting the SFC-MS selectivity and sensitivity was carried out. Under final conditions, a 2 mL volume of either red or white wine was extracted by SPE and analysed using external standard calibration achieving limits of quantification from 1 to 11 ng mL−1. Global recoveries ranged between 63 and 118%, depending on the compound and the spiked amount. When compared to UPLC performance, SFC resulted in a better separation of compounds, narrower peaks, comparable sensitivity and significantly lower matrix effects. The developed method allowed the quantification of imidacloprid in around half of the 25 commercial wine samples processed, all of them proceeding from grapes cultivated in year 2018 in the Northwest of Spain, with a maximum concentration of 33 ng mL−1. Acetamiprid was also detected in some white wine samples
PB Elsevier
SN 0021-9673
YR 2020
FD 2020
LK http://hdl.handle.net/10347/20872
UL http://hdl.handle.net/10347/20872
LA eng
NO L. Pérez-Mayán, M. Cobo-Golpe and M. Ramil et al., Evaluation of supercritical fluid chromatography accurate mass spectrometry for neonicotinoid compounds determination in wine samples, Journal of Chromatography A, https://doi.org/10.1016/j. chroma.2020.460963
NO This study was supported by Xunta de Galicia and Spanish Government through grants GRC-ED431C 2017/36 and PGC2018-094613-B-I00, both co-funded by the EU (FEDER). L. P-M acknowledges a FPU contract to the Spanish Ministry of Education(FPU16/03942)
DS Minerva
RD 24 abr 2026