RT Journal Article
T1 Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds
A1 Cambeiro Cambeiro, Fermín
A1 López Estévez, Susana
A1 Varela Carrete, Jesús Ángel
A1 Saá Rodríguez, Carlos
K1 Alkynyl derivatives
K1 Carbenes
K1 Cyclization
K1 Ruthenium
K1 Spiro compounds
AB A novel tandem Ru-catalyzed carbene addition to terminal alkynes/insertion of Csp3–H bonds in alkynyl acetals, ethers and amines has been accomplished under mild conditions. This cascade provides an efficient approach to form complex spiro and fused bicyclic structures in 1,5- and 1,6-hydride shift/cyclization sequences from vinylcarbene Ru intermediates.
PB Wiley
SN 1433-7851
YR 2011
FD 2011
LK http://hdl.handle.net/10347/23339
UL http://hdl.handle.net/10347/23339
LA eng
NO Cambeiro, F., López, S., Varela, J. A., Saá, C. (2012). Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds. Angew. Chem. Int. Ed., 51, 3, 723-727
NO NOTICE: This is the peer reviewed version of the following article: Cambeiro, F., López, S., Varela, J. A., Saá, C. (2017). Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds. Angew. Chem. Int. Ed. 2012, 51, 3, 723-727.[doi: 10.1002/anie.201107344]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archiving
NO We thank the MICINN [Projects CTQ2008-06557, CTQ2011-28258, Consolider Ingenio 2010 (CSD2007-00006)] and Xunta de Galicia (2007/XA084 and CN2011/054) for financial support. F. C. thanks the Xunta de Galicia and MICINN for a predoctoral grant
DS Minerva
RD 23 abr 2026