RT Journal Article
T1 Modular supramolecular capsules based on α,γ-cyclic peptide dimers for the development of confined catalysis
A1 Troncoso Mondragón, Ezequiel
A1 Fuertes, Alberto
A1 Calvelo Souto, Martín
A1 Fuentes de Arriba, Ángel Luis
A1 Amorín López, Manuel
A1 Granja Guillán, Juan Ramón
AB A modular strategy is designed for the preparation of supramolecular capsules in the search for new functional containers. The strategy is based on the use of the self-assembly properties of an α,γ-cyclic octapeptide to form toroidal dimers in which two reactive points are incorporated to anchor molecular caps in the last stage of the synthesis. In this way, the used caps, which are decorated with a catalytic metal complex, are easily interchangeable allowing searching for new catalytic properties.
PB Royal Society of Chemistry
YR 2025
FD 2025-01-24
LK https://hdl.handle.net/10347/40802
UL https://hdl.handle.net/10347/40802
LA eng
NO The Spanish Agencia Estatal de Investigación (AEI) (PID2019-111126RB-100 and PID2022-142440NB-I00), the Xunta de Galicia (ED431C 2021/21 and Centro de investigación do Sistema Universitario de Galicia accreditation 2023-2027, ED431G 2023/03), and the European Union (European Regional Development Fund -ERDF) are gratefully acknowledge. We also thank the ORFEO-CINCA network and Mineco (RED2022- 134287-T). A. L. F. A. thanks the Spanish Agencia Estatal de Investigación (AEI) for a Juan de la Cierva fellowship (FJCI-2015-26847). E. T. M. thanks the Spanish Ministry of Universities for his FPI contract. Prof. Miquel Costas (University of Girona) is acknowledged for fruitful discussions about the reactivity of iron(ii) complexes.
DS Minerva
RD 24 abr 2026