RT Journal Article
T1 A novel zinc(II) complex with the ligand 2,20,200-(1,4,7-triazanonane-1,4,7-triyl)- triacetate (NOTA)
A1 Pereira García, Iria
A1 Macías Luaces, Alejandro Alberto
A1 Bastida de la Calle, María Rufina
A1 Valencia Matarranz, Laura
K1 Single-crystal X-ray study
K1 T = 100 K
K1 Mean  (C–C) = 0.005 A˚
K1 R factor = 0.039
K1 WR factor = 0.084
K1 Data-to-parameter ratio = 16.6.
AB The zinc(II) complex with NOTA [2,20,200-(1,4,7-triazanonane1,4,7-triyl)triacetate] has previously been synthesized andstudied in solution, but was not isolated. The correspondingtitle ZnII complex pentasodium(I) bis{[2,20,200-(1,4,7-triazanonane-1,4,7-triyl)triacetato]zinc(II)} tris(perchlorate) methanolsolvate, Na5[Zn(C12H18N3O6)]2(ClO4)3 CH3OH, was crystallized as a sodium perchlorate double salt in methanol solution.The asymmetric unit contains two independent [Zn(NOTA)]complex anion entities, five sodium cations, three perchlorateanions and a methanol solvent molecule. The two ZnII cationsexhibit a distorted trigonal-prismatic N3O3 coordination witha bifacial arrangement of the donor atoms. Neither themethanol solvent molecule nor the perchlorate anions appearto be coordinated to the Zn centres. The crystal structureshows a layer arrangement parallel to (001) generated byinteractions between the [Zn(NOTA)] units, the Na+ cations,two ClO4 units and the methanole molecule, leading to anoverall layer composition of [Na5[Zn(C12H18N3O6)]2(ClO4)2.-CH3OH]+. The third ClO4 anion is isolated and situatedbetween the layers without any significant interactions
PB Int Union Crystallography
SN 2056-5368
YR 2009
FD 2009
LK http://hdl.handle.net/10347/23120
UL http://hdl.handle.net/10347/23120
LA eng
NO Pereira García, Iria ; Macías, Alejandro ; Bastida, Rufina ; Valencia, Valencia. (2009). A novel zinc(II) complex with the ligand 2,20,200-(1,4,7-triazanonane-1,4,7-triyl)- triacetate (NOTA). "Acta Crystallographica Section E",  E65, m84–m85
NO We thank the Xunta de Galicia (Spain; Project PGIDIT07PXIB209039PR) for financial support. The X-ray data were collected at the Unidade de Raios X, RIAIDT, University of Santiago de Compostela, Spain
DS Minerva
RD 25 abr 2026