RT Journal Article
T1 Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets
A1 Coronado, Eugenio
A1 Galán Mascarós, José R.
A1 Giménez López, María del Carmen
A1 Almeida, Manuel
A1 Waerenborgh, João Carlos
K1 Coordination chemistry
K1 Molecular materials
K1 Spin crossover
K1 Magnetic properties
K1 Mössbauer spectroscopy
AB We present the synthesis and structural characterization of the salt [Fe(bpp)2][MnCr(ox)3]2 · bpp · CH3OH. It crystallizes in the monoclinic space group. This material contains an anionic [MnCr(ox)3]− 3D 10-gon ferromagnetic network, that orders below 3.0 K. The channels created by this architecture are filled by the spin crossover cations [Fe(bpp)2]2+ (bpp = 2,6(bispyrazol-3-yl)pyridine), free ligand and solvent molecules. No spin transition has been observed at ambient pressure.
PB Elsevier
SN 0277-5387
YR 2006
FD 2006
LK http://hdl.handle.net/10347/32319
UL http://hdl.handle.net/10347/32319
LA eng
NO Coronado, E., Galán Mascarós, J.R., Giménez-López, M.C., Almeida, M., Waerenborgh, J.C. (2006). Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets. "Polyhedron". Vol.26, n. 9–11, 1838-1844
NO This work was supported by the European Union (Network of Excellence: MAGMANET). Financial support from the Ministerio de Educación y Ciencia (Projects MAT2004-3849 and BQU2002-01091), and from the Generalitat Valenciana (GV04A/77) is also acknowledged.
DS Minerva
RD 26 abr 2026