RT Journal Article T1 Transition Metal-mediated Reactions in Biological Media A1 Martínez-Calvo, Miguel A1 Mascareñas Cid, José Luis K1 Artificial metalloenzymes K1 Bioorthogonal K1 Living cells K1 Organometallic K1 Transition metal catalysis AB Transition-metal catalysis has changed the way in which chemical reactions can be accomplished. While most metal-catalyzed reactions have been achieved in organic solvents, recent work has demonstrated that many of these transformations can be made compatible with water. These discoveries have stimulated the search for metal catalysts that are capable of achieving designed reactions in biological settings, and eventually behave as non-natural enzymes working in native cellular environments. Although this new field of research is still taking its first steps, there is a growing number of publications in the area, and one can predict that it will steadily grow in the years to come. Here we will briefly review some of the main contributions in the area. The contents have been organized according to the type of transformation and transition metal catalysts involved in the process PB Swiss Chemical Society SN 0009-4293 YR 2018 FD 2018 LK http://hdl.handle.net/10347/18463 UL http://hdl.handle.net/10347/18463 LA eng NO Martínez-Calvo, M., & Mascareñas, J. (2018). Transition Metal-mediated Reactions in Biological Media. CHIMIA International Journal For Chemistry, 72(11), 791-801. doi: 10.2533/chimia.2018.791 DS Minerva RD 25 abr 2026