RT Journal Article
T1 Aromatic aldehyde oxidation by hexacyanoferrate(III) catalyzed by Ru(VI) in alkaline medium
A1 Alcolado Olivares, Clara Inés
A1 Poblete Pérez, Javier
A1 García Río, Luis
A1 Jiménez Martínez, Elena
A1 Poblete Martín, Francisco Javier
K1 Oxidation mechanism
K1 Aromatic aldehydes
K1 Ruthenate ion
K1 Hexacyanoferrate(III)
K1 Alkaline medium
AB In this study, the selective oxidation of aromatic aldehydes has been investigated using Ru(VI) as a catalyst and hexacyanoferrate (III) as a cooxidant in an alkaline medium. The reaction order with respect to the oxidant and the aromatic aldehyde is complex while the reaction order with respect to Ru(VI) is one. The proposed mechanism presents two catalytic cycles for the two active species of the catalyst. In each cycle, Ru(VI) species forms a complex with the anion of hydrated benzaldehyde which decomposes to form benzoic acid. The function of hexacyanoferrate(III) is the regeneration of catalyst species. A quantitative structure–activity relationship was analyzed using the Hammett equation for decomposition complex step. This analysis showed that deactivating groups in para- position enhances this process
PB Elsevier
SN 0167-7322
YR 2024
FD 2024-01-01
LK https://hdl.handle.net/10347/44400
UL https://hdl.handle.net/10347/44400
LA eng
NO C.I. Alcolado, J. Poblete, L. García-Río, E. Jiménez, F.J. Poblete, Aromatic aldehyde oxidation by hexacyanoferrate(III) catalyzed by Ru(VI) in alkaline medium, Journal of Molecular Liquids, Volume 393, 2024, 123580, ISSN 0167-7322, https://doi.org/10.1016/j.molliq.2023.123580
NO inancial support from the University of Castilla-La Mancha and the European Regional Development Fund (FEDER) (grant n° 2023-GRIN-34143) is gratefully acknowledged
DS Minerva
RD 28 abr 2026