RT Journal Article T1 Centennial Fertilization-Induced Soil Processes Control Trace Metal Dynamics. Lessons from a Long-Term Bare Fallow Experiment A1 van Oort, Folkert A1 Paradelo Núñez, Remigio A1 Proix, Nicolás A1 Delarue, Ghislaine A1 Baize, Denis A1 Monna, Fabrice K1 Fertilization K1 Bare fallow soils K1 Long-term agronomic experiments K1 Loess Luvisol K1 Acidification K1 Lixiviation K1 Clay leaching K1 Geochemical budgets K1 Major elements K1 Trace metals AB Long-term bare fallow (LTBF) experiments with historical sample archives offer uniqueopportunities to study long-term impacts of anthropogenic activities on mineral soil fractions.In natural agro- and ecosystems, such impacts are often masked by organic matter due to itsbuffering action and rapid turnover. The 42-plot LTBF trial of INRA (Institut National de la RechercheAgronomique) started in Versailles (France) in 1928 to assess the impacts of prolonged application offertilizers and amendments on the composition and properties of loamy soils. Here, we establishedgeochemical budgets of major and trace elements on surface samples from 1929 and 2014 for fourgroups of treatments relevant for developed soil processes. We considered accompanying effects ofsoil compaction or decompaction due to changing physicochemical conditions over 85 years. Elementlosses from the surface horizon were quantified via fertilization-induced or -amplified soil processes:clay leaching favored by Na- or K-based fertilization, and lixiviation of major and trace elementsin acidic or alkaline soil conditions. Enhanced mineral weathering was shown for acidified andnonamended plots. Conclusions on trace metal migration were confirmed by selected analyses onsubsurface horizons. Additional information was provided on specific element inputs via fertilizersand/or diffuse inputs via atmospheric deposition PB MDPI YR 2018 FD 2018 LK http://hdl.handle.net/10347/19970 UL http://hdl.handle.net/10347/19970 LA eng NO Van Oort, F., Paradelo, R., Proix, N., Delarue, G., Baize, D., & Monna, F. (2018). Centennial Fertilization-Induced Soil Processes Control Trace Metal Dynamics. Lessons from a Long-Term Bare Fallow Experiment. Soil Systems, 2(2), 23. NO Financial support came from INRA and from the Agence de l’Environnement et de la Maîtrise de l’Energie ADEME DS Minerva RD 28 abr 2026