RT Journal Article T1 Ruthenium bipyridyl complexes as photocleavable dimerizers: deactivation of DNA-binding peptides using visible light A1 Mosquera Mosquera, Jesús A1 Sánchez López, Mateo Isidro A1 Vázquez Sentís, Marco Eugenio A1 Mascareñas Cid, José Luis AB We report a photolabile biselectrophilic Ru(II) complex that can be used for homo- or heterodimerization of cysteine-containing peptides. The resulting dimers can be efficiently disassembled by long-wavelength light. As proof-of-concept, we describe the preparation of homo- and heterodimeric bZIP peptides whose DNA-binding properties can be turned off using visible light PB Royal Society of Chemistry SN 1364-548X YR 2014 FD 2014-07-28 LK http://hdl.handle.net/10347/11968 UL http://hdl.handle.net/10347/11968 LA eng NO Mosquera, J., Sánchez, M. I., Vázquez, M. E. and Mascareñas, J. L. (2014), Ruthenium bipyridyl complexes as photocleavable dimerizers: deactivation of DNA-binding peptides using visible light. Chem. Commun., 50, 10975-10978 [doi: 10.1039/C4CC04512B] NO Spanish MINECO. Grant Numbers: SAF2010-20822-C02-01/02, CTQ2010-20714-C02-01/BQU, CSD2007-00006ERDFXunta de Galicia. Grant Numbers: GRC2010/12, GR2013-041, INCITE09 209084PR, EM2013/036European Research Council. Grant Number: 340055CAM. Grant Number: S2009/PPQ-1634, AVANCAT DS Minerva RD 26 abr 2026