RT Journal Article
T1 Reaction Mechanisms of Single Metal Site Catalysts Supported on Covalent Organic Frameworks
A1 Gopakumar, Aswin
A1 Ortuño Maqueda, Manuel Ángel
A1 Lloret-Fillol, Julio
K1 COF
K1 Reaction mechanisms
K1 Single metal site
K1 CO2RR
K1 OER
AB Covalent organic frameworks (COFs) have become a versatile platform to immobilize a wide variety of single-atom metal catalysts. The resulting post-synthetic modified materials present a spectrum of valuable properties ranging from homogeneous to heterogeneous systems, such as well-defined catalytic sites, selectivity, recyclability, and stability. In this minireview, we discuss selected contributions that provide experimental and computational details on reaction mechanisms (e. g., via EXAFS, TEM, and DFT) catalyzed by single-atom metals embedded within the COF structure. When applicable, we highlight the different behaviour between molecular (homogeneous) and COF-supported (heterogeneous) sites regarding catalytic performance. With this survey, we aim to decipher the key features that aid in seeing COFs as not merely passive supports but as active items in catalysis.
PB Wiley
YR 2024
FD 2024
LK http://hdl.handle.net/10347/34595
UL http://hdl.handle.net/10347/34595
LA eng
NO A. Gopakumar, M. A. Ortuño, J. Lloret-Fillol. Reaction Mechanisms of Single Metal Site Catalysts Supported on Covalent Organic Frameworks. ChemCatChem 2024, e202400100
NO This work has received financial support from MCIN/ AEI/10.13039/501100011033 (PID2020-119116RA-I00, M.A.O.), Xunta Distinguished Researcher program (ED431H 2020/21), the Xunta de Galicia (Centro singular de investigación de Galicia acreditacion 2019–2022, ED431G 2019/03) and the European Union (European Regional Development Fund - ERDF). A.G. acknowledges the funding from the European Union's Horizon Europe research and innovation programme under the Marie Skłodowska-Curie grant agreement No.101105451. The authors also acknowledge the financial support of the ICIQ Foundation, the CERCA Program/Generalitat de Catalunya, MCIN through Severo Ochoa Excellence Accreditation 2020–2023 (CEX2019-000925-S, MIC/AEI), AGAUR (2021 SGR 01260), MCIN (PID2019-110050RB-I00, J.L-F.; PDC2022-133451-I00, J.L-F., PID2022-140142OB-I00) and “la Fundación Ramón Areces“ (ElectroFuel).
DS Minerva
RD 28 abr 2026