RT Journal Article
T1 A Two-Step, Stereoselective Synthesis of Nine- and Ten-Membered Carbocycles from Phthalates
A1 Prado, Gustavo
A1 Veiga, Alberte X.
A1 Fernández-Nieto, Fernando
A1 Paleo Pillado, María Rita
A1 Sardina López, Francisco Javier
AB A two-step, stereoselective procedure for the synthesis of nine- and ten-membered carbocycles from readily available phthalates is described. A variety of dialkyl phthalates have been transformed into [6,n]-fused bicyclo systems (n = 5, 6, 7) by a dearomatization/cyclization process and then converted into cyclonona- and cyclodecadienes through a bond cleavage reaction, whereby both processes are promoted by alkaline metals in THF
PB American Chemical Society
SN 1523-7060
YR 2015
FD 2015
LK http://hdl.handle.net/10347/16987
UL http://hdl.handle.net/10347/16987
LA eng
NO Prado, G., Veiga, A., Fernández-Nieto, F., Paleo, M., & Sardina, F. (2015). A Two-Step, Stereoselective Synthesis of Nine- and Ten-Membered Carbocycles from Phthalates. Org. Lett., 17(9), 2054-2057. doi: 10.1021/acs.orglett.5b00552
NO This work was supported by the Spanish MINECO(CTQ2011-22436), and the Xunta de Galicia (GRC2014/029)
DS Minerva
RD 22 abr 2026