RT Journal Article
T1 Vinyl Dihydropyrans and Dihydrooxazines: Cyclizations of Catalytic Ruthenium Carbenes Derived from Alkynals and Alkynones
A1 Cambeiro Cambeiro, Fermín
A1 López Estévez, Susana
A1 Varela Carrete, Jesús Ángel
A1 Saá Rodríguez, Carlos
K1 Alkynes
K1 Carbenes
K1 Cyclization
K1 Heterocycles
K1 Ruthenium
AB A novel synthesis of 2‐vinyldihydropyrans and dihydro‐1,4‐oxazines (morpholine derivatives) from alkynals and alkynones has been developed. The cyclizations require a mild generation of catalytic ruthenium carbenes from terminal alkynes and (trimethylsilyl)diazomethane followed by trapping with carbonyl nucleophiles. Mechanistic aspects of the new cyclizations are discussed.
PB Wiley
SN 1433-7851
YR 2014
FD 2014
LK http://hdl.handle.net/10347/23343
UL http://hdl.handle.net/10347/23343
LA eng
NO Cambeiro, F., López, S., Varela, J. A., Saá, C. (2014). Vinyl Dihydropyrans and Dihydrooxazines: Cyclizations of Catalytic Ruthenium Carbenes Derived from Alkynals and Alkynones. Angew. Chem. Int. Ed., 53, 23, 5959-5963
NO NOTICE: This is the peer reviewed version of the following article: Cambeiro, F., López, S., Varela, J. A., Saá, C. (2014). Vinyl Dihydropyrans and Dihydrooxazines: Cyclizations of Catalytic Ruthenium Carbenes Derived from Alkynals and Alkynones. Angew. Chem. Int. Ed., 53, 23, 5959-5963. [doi: 10.1002/anie.201400675]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archiving
NO This work was supported by MICINN (Spain) [projects CTQ2011-28258, Consolider Ingenio 2010 (CSD2007-0006)] and Xunta de Galicia and the European Regional Development Fund (project CN2011/054 and EM 2012/051). F.C. thanks XUGA for a predoctoral contract
DS Minerva
RD 27 abr 2026