Synthesis of triols with C3 symmetry by ring opening of tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione with nucleophiles
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Abstract
The reaction of tris(oxiran-2-ylmethyl)-1,3,5-triazinane-2,4,6-trione with phenol or N-methylaniline promoted by microwave heating, under solventless conditions, led to the opening of the oxirane ring through the less hindered carbon, leading to tripodal triols with C3 symmetry in good yields
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The 15th International Electronic Conference on Synthetic Organic Chemistry session Microwave Assisted Synthesis
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Proceedings of the 15th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2011, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-15-00690
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https://doi.org/10.3390/ecsoc-15-00690Sponsors
Xunta de Galicia for financial support: INCITE09 262346PR. X. F. thanks the Isidro Parga Pondal Program (Xunta de Galicia, Spain)
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© 2011 The author(s). Published by MDPI, Basel, Switzerland. Open Access