Bifunctional Skipped Dienes through Cu/Pd-Catalyzed Allylboration of Alkynes with B2pin2 and Vinyl Epoxides

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.authorVázquez Galiñanes, Nuria
dc.contributor.authorVelo Heleno, Isabel
dc.contributor.authorFañanás-Mastral, Martín
dc.date.accessioned2022-12-30T13:27:46Z
dc.date.available2022-12-30T13:27:46Z
dc.date.issued2022
dc.description.abstractA method for the use of vinyl epoxides in catalytic allylboration of alkynes is described. This transformation allows for the synthesis of bifunctional skipped dienes bearing both an allylic alcohol and an alkenylboronate from simple starting materials with high regio- and stereoselectivity. These two functionalities provide these products with highly versatile reactivity, as shown by their stereocontrolled conversion into cyclic boron compounds and polyenes.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipFinancial support from AEI (PID2020-118237RB-I00), the European Research Council (863914), the Xunta de Galicia (Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03), and the European Regional Development Fund (ERDF) is gratefully acknowledged. N.V.-G. thanks AEI for an FPI Predoctoral Fellowshipgl
dc.identifier.citationhttps://doi.org/10.1021/acs.orglett.2c03390gl
dc.identifier.doi10.1021/acs.orglett.2c03390
dc.identifier.essn1523-7052
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10347/29690
dc.language.isoenggl
dc.publisherACS Publicationsgl
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-118237RB-I00/ESgl
dc.relation.publisherversionhttps://doi.org/10.1021/acs.orglett.2c03390gl
dc.rights© 2022 The Authors. Published by American Chemical Society. This work is under a CC Attribution 4.0 International (CC BY 4.0)gl
dc.rightsAtribución 4.0 Internacional
dc.rights.accessRightsopen accessgl
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectChemical reactionsgl
dc.subjectEthersgl
dc.subjectHydrocarbonsgl
dc.subjectInorganic carbon compoundsgl
dc.subjectVinylgl
dc.titleBifunctional Skipped Dienes through Cu/Pd-Catalyzed Allylboration of Alkynes with B2pin2 and Vinyl Epoxidesgl
dc.typejournal articlegl
dc.type.hasVersionVoRgl
dspace.entity.typePublication
relation.isAuthorOfPublication9dca33cc-3c8d-4d1c-8644-76987c972089
relation.isAuthorOfPublication.latestForDiscovery9dca33cc-3c8d-4d1c-8644-76987c972089

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