[C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insights

Simple item page
dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorGonzález, Jorge A.
dc.contributor.authorVerdugo Leal, Felipe Ignacio
dc.contributor.authorMascareñas Cid, José Luis
dc.contributor.authorLópez García, Fernando
dc.contributor.authorNevado, Cristina
dc.date.accessioned2020-11-03T13:08:39Z
dc.date.available2021-07-16T01:00:11Z
dc.date.issued2020
dc.descriptionThis is the peer reviewed version of the following article: J. A. González, F. Verdugo, J. L. Mascareñas, F. López, C. Nevado, Angew. Chem. Int. Ed. 2020, 59, 20049, which has been published in final form at https://doi.org/10.1002/anie.202007371. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions.gl
dc.description.abstractPyridine‐substituted alkylidenecyclopropanes (Py‐ACPs) react with gold(III) salts under mild reaction conditions through an unprecedented, proximal ring‐opening pathway, to generate highly appealing, catalytically active pyridine alkenyl [C^N]‐gold(III) species. Mechanistic studies reveal that the activation of the C−C bond of the ACP takes place through an unusual concerted, σ‐bond metathesis type‐processgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipWe thank the European Research Council (ERC Starting grant agreement no. 307948, and Advanced Grant 340055), the Swiss National Science Foundation (SNF 200020_146853), the Legerlotz Stiftung the MINECO (SAF2016‐76689‐R, CTQ2017‐84767‐P), the Xunta de Galicia (2015‐CP082, ED431C 2017/19, and Centro singular de investigación de Galicia accreditation 2019–2022, ED431G 2019/03) and the European Union (European Regional Development Fund—ERDF) for financial support and the STSM Grant to F. Verdugo from COST Action CA15106gl
dc.identifier.citationJ. A. González, F. Verdugo, J. L. Mascareñas, F. López, C. Nevado, Angew. Chem. Int. Ed. 2020, 59, 20049gl
dc.identifier.doi10.1002/anie.202007371
dc.identifier.essn1521-3773
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/10347/23539
dc.language.isoenggl
dc.publisherWileygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/307948
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/340055
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/SAF2016‐76689‐R/ES
dc.relation.publisherversionhttps://doi.org/10.1002/anie.202007371gl
dc.rights© 2020 Wiley-VCH. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versionsgl
dc.rights.accessRightsopen accessgl
dc.subject[C^N] cyclometalated gold(III)gl
dc.subjectAlkylidenecyclopropanesgl
dc.subjectC−C activationgl
dc.subjectGoldgl
dc.subjectσ-bond metathesisgl
dc.title[C^N]‐Alkenyl Gold(III) Complexes by Proximal Ring‐Opening of (2‐Pyridyl)alkylidenecyclopropanes: Mechanistic Insightsgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication5ae222c9-f626-432b-aac5-da78c06ed64f
relation.isAuthorOfPublication.latestForDiscovery5ae222c9-f626-432b-aac5-da78c06ed64f

Files

Original bundle

Now showing 1 - 1 of 1
Thumbnail Image
Name:
2020_AngewChemIntEd_Gonzalez_Alkeynyl_Gold.pdf
Size:
1.73 MB
Format:
Adobe Portable Document Format
Description:
Download

Collections

Centro de Investigación en Química Biolóxica e Materiais Moleculares (CiQUS)
Química Orgánica