Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizations

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorVarela Fernández, Alejandro
dc.contributor.authorVarela Carrete, Jesús Ángel
dc.contributor.authorSaá Rodríguez, Carlos
dc.date.accessioned2020-10-05T06:34:56Z
dc.date.available2020-10-05T06:34:56Z
dc.date.issued2012
dc.descriptionNOTICE: This is the peer reviewed version of the following article: Varela-Fernández, A., Varela, J. A., Saá, C. (2012). Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizations. Synthesis, 44, 21, 3285-3295. [doi: 10.1055/s-0032-1316539]. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archivinggl
dc.description.abstractIndoles, dihydroisoquinolines and dihydroquinolines were efficiently prepared by ruthenium-catalyzed heterocyclizations of aromatic homo- and bis-homopropargyl amines/amides in the presence of an amine/ammonium base-acid pair. These regioselective 5- and 6-endo cyclizations most probably occur by nucleophilic trapping of key Ru vinylidene intermediates.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipWe thank the MICINN [Project CTQ2011-28258, Consolider Ingenio 2010 (CSD2007-00006)], Xunta de Galicia and European Regional Development Fund (2007/XA084 and CN2011/054) for financial support. A. V.-F- thanks the USC for a predoctoral contractgl
dc.identifier.citationVarela-Fernández, A., Varela, J. A., Saá, C. (2012). Formation of Indoles, Dihydroisoquinolines and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizations. Synthesis, 44, 21, 3285-3295gl
dc.identifier.doi10.1055/s-0032-1316539
dc.identifier.essn1437-210X
dc.identifier.issn0039-7881
dc.identifier.urihttp://hdl.handle.net/10347/23341
dc.language.isoenggl
dc.publisherThiemegl
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC/Plan Nacional de I+D+i 2004-2007/CSD2007-00006/ES/Desarrollo de entidades organometálicas para reacciones de funcionalización selectiva en moléculas orgánicas
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/CTQ2011-28258/ES/CATALISIS ORGANOMETALICA: FUNCIONALIZACION DE ENLACES C-H
dc.relation.publisherversionhttps://doi.org/10.1055/s-0032-1316539gl
dc.rights© Georg Thieme Verlag Stuttgart · New York. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archivinggl
dc.rights.accessRightsopen accessgl
dc.subjectHeterocyclizationsgl
dc.subjectIndolesgl
dc.subjectIsoquinolinesgl
dc.subjectQuinolinesgl
dc.subjectRutheniumgl
dc.subjectVinylidenesgl
dc.titleFormation of Indoles, Dihydroisoquinolines and Dihydroquinolines by Ruthenium-Catalyzed Heterocyclizationsgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublicatione9be05f9-b5a3-405c-aaf6-4e32700dd21d
relation.isAuthorOfPublication2c024eb2-7698-4785-bd0c-518f70068330
relation.isAuthorOfPublication.latestForDiscoverye9be05f9-b5a3-405c-aaf6-4e32700dd21d

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