On the Mechanism of Rhodium-Catalyzed [6+2] Cycloaddition of 2-Vinylcylobutanones and Alknenes

Montero Campillo, María de la Merced; Cabaleiro Lago, Enrique Manuel; Rodríguez Otero, Jesús

doi:10.3390/ecsoc-11-01369

On the Mechanism of Rhodium-Catalyzed [6+2] Cycloaddition of 2-Vinylcylobutanones and Alknenes

dc.contributor.affiliation	Universidade de Santiago de Compostela. Departamento de Química Física	gl
dc.contributor.author	Montero Campillo, María de la Merced
dc.contributor.author	Cabaleiro Lago, Enrique Manuel
dc.contributor.author	Rodríguez Otero, Jesús
dc.date.accessioned	2021-08-18T08:38:57Z
dc.date.available	2021-08-18T08:38:57Z
dc.date.issued	2007
dc.description	The 11th International Electronic Conference on Synthetic Organic Chemistry session Computational Chemistry	gl
dc.description.abstract	The intramolecular [6+2] cycloaddition mechanism of 2vinylcyclobutanones and alkenes catalyzed by the [Rh(CO)2Cl]2 dimer has been studied using density functional theory, comparing this multistep process with the onestep reaction in absence of catalyst. This possible mechanism agrees with what was previously experimentally suggested. Calculations have also allowed to explain the selectivity of the reaction	gl
dc.identifier.citation	Montero Campillo, M.M.; Cabaleiro Lago, E.M.; Rodríguez Otero, J. On the Mechanism of Rhodium-Catalyzed [6+2] Cycloaddition of 2-Vinylcylobutanones and Alknenes, in Proceedings of the 11th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2007, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-11-01369	gl
dc.identifier.doi	10.3390/ecsoc-11-01369
dc.identifier.isbn	3-906980-19-7
dc.identifier.uri	http://hdl.handle.net/10347/26833
dc.language.iso	eng	gl
dc.publisher	MDPI	gl
dc.relation.ispartofseries	Electronic Conference on Synthetic Organic Chemistry;11
dc.relation.publisherversion	https://doi.org/10.3390/ecsoc-11-01369	gl
dc.rights	© 2007 The author(s). Published by MDPI, Basel, Switzerland. Open Access	gl
dc.rights.accessRights	open access	gl
dc.title	On the Mechanism of Rhodium-Catalyzed [6+2] Cycloaddition of 2-Vinylcylobutanones and Alknenes	gl
dc.type	book part	gl
dspace.entity.type	Publication
relation.isAuthorOfPublication	cae389b7-4a38-481e-b348-4a3d4d6707fb
relation.isAuthorOfPublication	41c7b009-96a5-4225-97dc-0feda160d770
relation.isAuthorOfPublication.latestForDiscovery	cae389b7-4a38-481e-b348-4a3d4d6707fb

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