Supramolecular polymer formed by ditopic cyclodextrin and ditopic adamantane derivatives
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Abstract
Novel host-guest supramolecular copolymers have been prepared from a ß-cyclodextrin (binded to ethylenediamintetraacetic acid, EDTA) dimer and a ditopic guest with two adamantyl groups bound to pyromellitic acid. Molecular weight and molecular size were determined from static and dynamic light scattering measurements (SLS and DLS, respectively). The analysis of results suggests that the supramolecular polymer adopts a shruck structure with an average molecular weight value of Mn =(1.51±0.02)×104 g·mol-1 (degree of polymerization equal to 5)
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The 12th International Electronic Conference on Synthetic Organic Chemistry session Supramolecular Chemistry
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Antelo, A.; Alcalde, M.A.; Jover, A.; Meijide, F.; Galantini, L.; Tato, J.V. Supramolecular polymer formed by ditopic cyclodextrin and ditopic adamantane derivatives, in Proceedings of the 12th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2008, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-12-01270
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https://doi.org/10.3390/ecsoc-12-01270Sponsors
The authors from USC thank the Ministerio de Ciencia y Tecnología (Project MAT2004-04606) and Xunta de Galicia (PGIDIT05PXIC26201PN) for financial support
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© 2008 The author(s). Published by MDPI, Basel, Switzerland. Open Access