The chelate−to−bridging shift of phosphane dipalladacycles: convenient synthesis of double A‐frame tetranuclear complexes

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánica
dc.contributor.authorFrieiro Gomis, Pablo
dc.contributor.authorLucio Martínez, Fátima
dc.contributor.authorMunín Cruz, Paula
dc.contributor.authorOrtigueira Amor, Juan Manuel
dc.contributor.authorPereira Lorenzo, María Teresa
dc.contributor.authorPolo Ces, Paula
dc.contributor.authorVázquez García, Digna
dc.contributor.authorVila Abad, José Manuel
dc.date.accessioned2025-01-30T13:13:25Z
dc.date.available2025-01-30T13:13:25Z
dc.date.issued2018-02-19
dc.description.abstractPalladacycles of the type [Pd2(Ph2PCH2PPh2-P,P)2(C,N:C,N)] (C,N:C,N = bis(N-2,3,4-trimethoxybenzylidene)-4,4′-sulfonyldianiline or -4,4′-oxydianiline) can undergo a spontaneous slow chelate-to-bridging diphosphane coordination shift in solution. Following this strategy a tailor-made synthetic procedure was devised that culminates in isolation of double A-frame tetranuclear palladium complexes.
dc.description.peerreviewedSI
dc.identifier.citationFrieiro-Gomis, P., Lucio-Martínez, F., Munín-Cruz, P., M. Ortigueira, J., Teresa Pereira, M., Polo-Ces, P., Vázquez-García, D., & M. Vila, J. (2018). The chelate-to-bridging shift of phosphane dipalladacycles: Convenient synthesis of double A-frame tetranuclear complexes. “Chemical Communications”, 54(21), 2662-2665. https://doi.org/10.1039/C8CC01046C
dc.identifier.doi10.1039/C8CC01046C
dc.identifier.essn1364-548X
dc.identifier.issn1359-7345
dc.identifier.urihttps://hdl.handle.net/10347/39367
dc.issue.number21
dc.journal.titleChemical Communications
dc.language.isoeng
dc.page.final2665
dc.page.initial2662
dc.publisherRoyal Society of Chemistry
dc.relation.projectIDinfo:eu-repo/grantAgreement/MECD//FPU13%2F05014/ES/FPU13%2F05014/
dc.relation.projectIDinfo:eu-repo/grantAgreement/Xunta de Galicia/Grupos de Referencia Competitiva/GRC2014%2F042/
dc.relation.projectIDinfo:eu-repo/grantAgreement/Xunta de Galicia/Grupos de Referencia Competitiva/GRC2015%2F009/
dc.relation.publisherversionhttp://dx.doi.org/10.1039/C8CC01046C
dc.rights© The Royal Society of Chemistry, 2018
dc.rights.accessRightsopen access
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectPhosphane dipalladacycles
dc.subjectChelate-to-bridging
dc.subjectTetranuclear complexes
dc.subject.classification2303 Química inorgánica
dc.titleThe chelate−to−bridging shift of phosphane dipalladacycles: convenient synthesis of double A‐frame tetranuclear complexes
dc.typejournal article
dc.type.hasVersionAM
dc.volume.number54
dspace.entity.typePublication
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