Copper-catalyzed O-alkenylation of phosphonates

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorVázquez Galiñanes, Nuria
dc.contributor.authorAndón Rodríguez, Mariña
dc.contributor.authorGómez Roibás, Patricia
dc.contributor.authorFañanás-Mastral, Martín
dc.date.accessioned2020-04-27T10:00:33Z
dc.date.available2020-04-27T10:00:33Z
dc.date.issued2020
dc.description.abstractCopper catalysis allows the direct oxygen alkenylation of dialkyl phosphonates with alkenyl(aryl)iodonium salts with selective transfer of the alkenyl group. This novel methodology proceeds with a wide range of phosphonates under mild conditions and gives straightforward access to valuable enol phosphonates in very good yields.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipFinancial support from the AEI (CTQ2017-88451-R), Xunta de Galicia (ED431F 2016/006; ED431C 2018/04; Centro singular de investigación de Galicia accreditation 2016-2019, ED431G/09) and the European Union (ERDF) is gratefully acknowledged. N. V.-G. thanks AEI for a predoctoral FPI fellowship.gl
dc.identifier.citationVázquez-Galiñanes, N.; Andón-Rodríguez, M.; Gómez-Roibás, P.; Fañanás-Mastral, M. Beilstein J. Org. Chem. 2020, 16, 611–615. doi:10.3762/bjoc.16.56gl
dc.identifier.doi10.3762/bjoc.16.56
dc.identifier.essn1860-5397
dc.identifier.urihttp://hdl.handle.net/10347/21780
dc.language.isoenggl
dc.publisherBeilstein Institutegl
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-88451-R/ES/GENERACION NO CONVENCIONAL DE REACTIVOS ORGANOMETALICOS CATALITICOS PARA EL USO DE HIDROCARBUROS COMO MATERIAS PRIMAS EN REACCIONES DE FORMACION DE ENLACES CARBONO-CARBONO
dc.relation.publisherversionhttps://doi.org/10.3762/bjoc.16.56gl
dc.rights© 2020 Vázquez-Galiñanes et al.; licensee Beilstein-Institut. This is an Open Access article under the terms of the Creative Commons Attribution License (http://creativecommons.org/licenses/by/4.0). Please note that the reuse, redistribution and reproduction in particular requires that the authors and source are credited. The license is subject to the Beilstein Journal of Organic Chemistry terms and conditions: (https://www.beilstein-journals.org/bjoc)gl
dc.rights.accessRightsopen accessgl
dc.rights.urihttp://creativecommons.org/licenses/by/4.0
dc.subjectAlkenylationgl
dc.subjectCoppergl
dc.subjectC(sp2)–O Bond Formationgl
dc.subjectHypervalent Iodinegl
dc.subjectPhosphonatesgl
dc.titleCopper-catalyzed O-alkenylation of phosphonatesgl
dc.typejournal articlegl
dc.type.hasVersionVoRgl
dspace.entity.typePublication
relation.isAuthorOfPublication9dca33cc-3c8d-4d1c-8644-76987c972089
relation.isAuthorOfPublication.latestForDiscovery9dca33cc-3c8d-4d1c-8644-76987c972089

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