Poly(phenylacetylene) Amines: A General Route to Water-Soluble Helical Polyamines

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Medicina Molecular e Enfermidades Crónicasgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorSuárez Picado, Esteban
dc.contributor.authorQuiñoá Cabana, Emilio
dc.contributor.authorRiguera Vega, Ricardo
dc.contributor.authorFreire Iribarne, Félix Manuel
dc.date.accessioned2019-06-17T07:44:20Z
dc.date.available2019-09-12T01:00:09Z
dc.date.issued2018-09-12
dc.descriptionThis is the Accepted Manuscript version of a Published Work that appeared in final form in Chemistry of Materials, Copyright © 2018 American Chemical Society after peer review and technical edityng by the publisher. To access the final edited and published work see: https://pubs.acs.org/doi/10.1021/acs.chemmater.8b03238gl
dc.description.abstractPolyphenylacetylenes bearing prim- and secamine groups are barely known due to their poisoning activity towards the polymerization catalyst. Herein we prepare 11 different amino polymers in high yields by direct polymerization of their corresponding ammonium salts in water using [Rh(cod)2] +BF4- as catalyst. They are stable, water soluble, and show a helical structure that responds to external stimuli (polarity, pH and metal ions) acting on the pendants. The location of the amino group in the pendant is shown to be critical for the helical response to protonationgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipFinancial support from MINECO (CTQ2014-61470-EXP, CTQ2015-70519-P), Xunta de Galicia (GRC2014/040, Centro singular de investigación de Galicia accreditation 2016- 2019, ED431G/09) and the European Regional Development Fund (ERDF) is gratefully acknowledged. E. S. P. is grateful to MINECO for a FPU predoctoral fellowshipgl
dc.identifier.citationSuárez-Picado, E., Quiñoá, E., Riguera, R., & Freire, F. (2018). Poly(phenylacetylene) Amines: A General Route to Water-Soluble Helical Polyamines. Chemistry Of Materials, 30(19), 6908-6914. doi: 10.1021/acs.chemmater.8b03238gl
dc.identifier.doi10.1021/acs.chemmater.8b03238
dc.identifier.essn1520-5002
dc.identifier.issn0897-4756
dc.identifier.urihttp://hdl.handle.net/10347/18880
dc.language.isoenggl
dc.publisherAmerican Chemical Societygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2014-61470-EXP/ES/CATALIZADORES POLIMERICOS CON QUIRALIDAD REVERSIBLE
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2015-70519-P/ES/ATERIALES QUIROPTICOS MODULABLES A PARTIR DE POLIMEROS INTELIGENTES
dc.relation.publisherversionhttps://doi.org/10.1021/acs.chemmater.8b03238gl
dc.rightsCopyright © 2018 American Chemical Societygl
dc.rights.accessRightsopen accessgl
dc.titlePoly(phenylacetylene) Amines: A General Route to Water-Soluble Helical Polyaminesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication20b69c32-3d11-4383-896f-e2c8a0beca15
relation.isAuthorOfPublication0f51f559-1806-45ca-945e-f4c12c3cefb9
relation.isAuthorOfPublication2943e14b-a7a1-4b71-9bd4-74c28b79e935
relation.isAuthorOfPublication.latestForDiscovery20b69c32-3d11-4383-896f-e2c8a0beca15

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