Rhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorAraya, Marisel
dc.contributor.authorGulías Costa, Moisés
dc.contributor.authorFernández, Israel
dc.contributor.authorBhargava, Gaurav
dc.contributor.authorCastedo Expósito, José Luis
dc.contributor.authorMascareñas Cid, José Luis
dc.contributor.authorLópez García, Fernando
dc.date.accessioned2014-12-05T12:42:52Z
dc.date.available2017-08-29T01:00:16Z
dc.date.issued2014-07-17
dc.description.abstractA Rh-catalyzed intramolecular [3+2+2] cycloaddition is reported. The cycloaddition affords synthetically relevant 5,7,5-fused tricyclic systems of type 2 from readily available dienyne precursors. The transformation takes place with moderate or good yields, high diastereoselectivity, and total chemoselectivitygl
dc.description.peerreviewedSIgl
dc.description.sponsorshipSpanish MINECO. Grant Numbers: SAF2010-20822-C02-01/02, CTQ2010-20714-C02-01/BQU, CSD2007-00006 ERDF Xunta de Galicia. Grant Numbers: GRC2010/12, GR2013-041, INCITE09 209084PR, EM2013/036 European Research Council. Grant Number: 340055 CAM. Grant Number: S2009/PPQ-1634, AVANCATgl
dc.identifier.citationAraya, M., Gulías, M., Fernández, I., Bhargava, G., Castedo, L., Mascareñas, J. L. and López, F. (2014), Rhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenes. Chem. Eur. J., 20: 10255–10259. doi: 10.1002/chem.201402473gl
dc.identifier.doi10.1002/chem.201402473
dc.identifier.issn1521-3765
dc.identifier.urihttp://hdl.handle.net/10347/11966
dc.language.isoenggl
dc.publisherWILEY-VCH Verlag GmbHgl
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/340055
dc.relation.publisherversionhttp://dx.doi.org/10.1002/chem.201402473gl
dc.rights© WILEY-VCH Verlag GmbH & Co. KGaA, Weinheimgl
dc.rights.accessRightsopen accessgl
dc.subjectAlkylidenecyclopropanegl
dc.subjectCarbocyclesgl
dc.subjectCatalysisgl
dc.subjectCycloadditionsgl
dc.subjectRhodiumgl
dc.subject.classificationMaterias::Investigación::23 Química::2302 Bioquímicagl
dc.titleRhodium-Catalyzed Intramolecular [3+2+2] Cycloadditions between Alkylidenecyclopropanes, Alkynes, and Alkenesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication47a6a088-27a9-412e-8422-0de4fd8af0d4
relation.isAuthorOfPublication5ae222c9-f626-432b-aac5-da78c06ed64f
relation.isAuthorOfPublication.latestForDiscovery47a6a088-27a9-412e-8422-0de4fd8af0d4

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