Iterative catalyst controlled diastereodivergent synthesis of polypropionates

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorRoke, Diedrik
dc.contributor.authorFañanás-Mastral, Martín
dc.contributor.authorFeringa, Ben L.
dc.date.accessioned2018-07-06T12:43:17Z
dc.date.available2018-07-06T12:43:17Z
dc.date.issued2016-11-01
dc.description.abstractPolypropionate fragments are synthesized using a combination of a copper-catalyzed asymmetric allylic alkylation, ruthenium-catalyzed cross-metathesis and iridium-catalyzed asymmetric allylic etherification. The use of an appropriate chiral ligand for each catalytic reaction allows access to 1,2-hydroxymethyl arrays with good to excellent control over the relative and absolute configuration of the different stereocenters.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipFinancial support from The Netherlands Organization for Scientific Research (NWO-CW), the National Research School of Catalysis (NRSC-C) and the Ministry of Education, Culture and Science (Gravitation Program 024.001.035) is gratefully acknowledgedgl
dc.identifier.citationRoke, D., Fañanás-Mastral, M., & Feringa, B. (2016). Iterative catalyst controlled diastereodivergent synthesis of polypropionates. Organic Chemistry Frontiers, 3(11), 1383-1391. doi: 10.1039/c6qo00199hgl
dc.identifier.doi10.1039/c6qo00199h
dc.identifier.essn2052-4129
dc.identifier.urihttp://hdl.handle.net/10347/16978
dc.language.isoenggl
dc.publisherRoyal Society of Chemistrygl
dc.relation.publisherversionhttps://doi.org/10.1039/C6QO00199Hgl
dc.rights© The Royal Society of Chemistry 2016gl
dc.rights.accessRightsopen accessgl
dc.titleIterative catalyst controlled diastereodivergent synthesis of polypropionatesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication9dca33cc-3c8d-4d1c-8644-76987c972089
relation.isAuthorOfPublication.latestForDiscovery9dca33cc-3c8d-4d1c-8644-76987c972089

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