Competition between tunnel- and viscosity-effects on bimolecular hydrogen-transfer reaction

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Físicagl
dc.contributor.authorKensy, Uwe
dc.contributor.authorGrellmann, Karl-Heinz
dc.contributor.authorMosquera González, Manuel
dc.date.accessioned2018-07-27T12:11:26Z
dc.date.available2018-07-27T12:11:26Z
dc.date.issued1993
dc.description.abstractThe photocyclization of a methylsubstituted diphenylamine results in the formation of a transient zwitterionic dihydrocarbazole. The transient converts into a stable dihydrocarbazole by an intramolecular, sigmatropic hydrogen shift and by an intermolecular hydrogen exchange reaction. The rates of both reactions are governed by hydrogen tunnel effects. The intermolecular hydrogen exchange is the first example for a bimolecular reaction where tunnel effects have been observed. The role of solvent viscosity is discussedgl
dc.description.peerreviewedSIgl
dc.identifier.citationKensy, U., Grellmann, K.-H. & Mosquera González, M. (1993). Competition between tunnel- and viscosity-effects on bimolecular hydrogen-transfer reaction. Pure and Applied Chemistry, Vol. 65, No. 8, pp. 1625–1628. https://doi.org/10.1351/pac199365081625gl
dc.identifier.doi10.1351/pac199365081625
dc.identifier.essn1365-3075
dc.identifier.issn0033-4545
dc.identifier.urihttp://hdl.handle.net/10347/17085
dc.language.isoenggl
dc.publisherInternational Union of Pure and Applied Chemistrygl
dc.relation.publisherversionhttp://dx.doi.org/10.1351/pac199365081625gl
dc.rights@ 1993 IUPACgl
dc.rights.accessRightsopen accessgl
dc.titleCompetition between tunnel- and viscosity-effects on bimolecular hydrogen-transfer reactiongl
dc.typejournal articlegl
dc.type.hasVersionVoRgl
dspace.entity.typePublication
relation.isAuthorOfPublication69b254b2-85d9-4480-b0d0-0e02da0deccd
relation.isAuthorOfPublication.latestForDiscovery69b254b2-85d9-4480-b0d0-0e02da0deccd

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