Oxidation of Alkynes via Catalytic Metal-Vinylidenes

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorÁlvarez Pérez, Andrea
dc.contributor.authorSaá Rodríguez, Carlos
dc.contributor.authorVarela Carrete, Jesús Ángel
dc.date.accessioned2020-10-05T07:20:13Z
dc.date.available2021-06-15T01:00:09Z
dc.date.issued2020
dc.descriptionNOTICE: This is the peer reviewed version of the following article: Álvarez-Pérez, A., Saá, C., Varela, J. A. (2020). Oxidation of Alkynes via Catalytic Metal-Vinylidenes. Synthesis, 52, 18, 2639-2649. [doi: 10.1055/s-0040-1707860]. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archivinggl
dc.description.abstractMetal-vinylidenes, generated by treatment of terminal alkynes with transition metals, are very useful intermediates in modern synthetic chemistry as shown by the high number of transformations in which they are involved. When a metal-vinylidene is generated in the presence of an oxidant, its immediate oxidation to a ketene intermediate occurred. In this short review, recent synthetic applications of the oxidation of alkynes via ketene intermediates from initially formed metal-vinylidenes are highlighted.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipThis work has received financial support from MINECO (project CTQ2017-87939R and ORFEO-CINQA network RED2018-102387-T), the Xunta de Galicia (project ED431C 2018/04 and Centro singular de investigación de Galicia accreditation 2019-2022, ED431G 2019/03) and the European Union (European Regional Development Fund – ERDF)gl
dc.identifier.citationÁlvarez-Pérez, A., Saá, C., Varela, J. A. (2020). Oxidation of Alkynes via Catalytic Metal-Vinylidenes. Synthesis, 52, 18, 2639-2649gl
dc.identifier.doi10.1055/s-0040-1707860
dc.identifier.essn1437-210X
dc.identifier.issn0039-7881
dc.identifier.urihttp://hdl.handle.net/10347/23361
dc.language.isoenggl
dc.publisherThiemegl
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/CTQ2017-87939-R/ES/NUEVAS RUTAS CATALITICAS A PAHS (HIDROCARBUROS AROMATICOS POLICICLICOS) DOPADOS Y HETEROCICLOS BIOACTIVOS
dc.relation.publisherversionhttps://doi.org/10.1055/s-0040-1707860gl
dc.rights© Georg Thieme Verlag Stuttgart · New York. This article may be used for non-commercial purposes in accordance with Thieme Terms and Conditions for self-archivinggl
dc.rights.accessRightsopen accessgl
dc.subjectAmidesgl
dc.subjectCyclizationgl
dc.subjectEstersgl
dc.subjectβ-Lactamsgl
dc.subjectKetenesgl
dc.subjectVinylidenesgl
dc.titleOxidation of Alkynes via Catalytic Metal-Vinylidenesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication2c024eb2-7698-4785-bd0c-518f70068330
relation.isAuthorOfPublicatione9be05f9-b5a3-405c-aaf6-4e32700dd21d
relation.isAuthorOfPublication.latestForDiscovery2c024eb2-7698-4785-bd0c-518f70068330

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