Gold(I)‐Catalyzed Intermolecular [2+2] Cycloadditions between Allenamides and Alkenes
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Abstract
3‐(Propa‐1,2‐dien‐1‐yl)oxazolidin‐2‐one works as an efficient two‐carbon partner in a variety of intermolecular gold‐catalyzed [2+2] cycloadditions to alkenes. The transformation represents a simple and practical entry to highly substituted cyclobutane derivatives and takes place with complete regio‐ and stereocontrol
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This is the peer reviewed version of the following article: Faustino, H. , Bernal, P. , Castedo, L. , López, F. and Mascareñas, J. L. (2012), Gold(I)‐Catalyzed Intermolecular [2+2] Cycloadditions between Allenamides and Alkenes. Adv. Synth. Catal., 354: 1658-1664, which has been published in final form at https://doi.org/10.1002/adsc.201200047. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions
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Faustino, H. , Bernal, P. , Castedo, L. , López, F. and Mascareñas, J. L. (2012), Gold(I)‐Catalyzed Intermolecular [2+2] Cycloadditions between Allenamides and Alkenes. Adv. Synth. Catal., 354: 1658-1664. doi:10.1002/adsc.201200047
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https://doi.org/10.1002/adsc.201200047Sponsors
Spanish MEC. Grant Number: SAF2007‐61015, SAF2010‐20822‐C02 Consolider‐Ingenio 2010. Grant Number: CSD2007‐00006 ERDF CSIC Xunta de Galicia. Grant Number: INCITE09 209 122 PR and GRC2010/12
Fundação para a Ciência e a Tecnologia‐Portugal. Grant Number: PhD Grant SFRH/BD/60214/2009
Spanish MICINN Johnson‐Matthey
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© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versions