Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorChaves Pouso, Andrea
dc.contributor.authorRivera Chao, Eva
dc.contributor.authorFañanás-Mastral, Martín
dc.date.accessioned2020-10-09T06:55:30Z
dc.date.available2021-09-08T01:00:09Z
dc.date.issued2020
dc.description.abstractA copper-catalyzed protoboration of borylated dendralenes is reported. The method employs an NHC–Cu catalyst and provides access to 1,4-addition products with excellent levels of chemo-, regio- and stereoselectivity. The resulting diene bis(boronates) are oxidized to the corresponding diene diols which are synthetically versatile building blocks.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipFinancial support from the AEI (CTQ2017-88451-R), Xunta de Galicia (ED431C 2018/04; Centro singular de investigación de Galicia accreditation 2019–2022, ED431G 2019/03) and the European Union (European Regional Development Fund – ERDF) is gratefully acknowledged. E. R.-C. thanks Xunta de Galicia for predoctoral fellowshipgl
dc.identifier.citationChaves-Pouso, A., Rivera-Chao, E., & Fañanás-Mastral, M. (2020). Copper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienes. Chemical Communications. https://doi.org/10.1039/d0cc04018egl
dc.identifier.doi10.1039/D0CC04018E
dc.identifier.essn1364-548X
dc.identifier.urihttp://hdl.handle.net/10347/23373
dc.language.isoenggl
dc.publisherRoyal Society of Chemistrygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2017-88451-R/ES/GENERACION NO CONVENCIONAL DE REACTIVOS ORGANOMETALICOS CATALITICOS PARA EL USO DE HIDROCARBUROS COMO MATERIAS PRIMAS EN REACCIONES DE FORMACION DE ENLACES CARBONO-CARBONO
dc.relation.publisherversionhttps://doi.org/10.1039/D0CC04018Egl
dc.rights© The Royal Society of Chemistry 2020. This article may be used for non- commercial purposes in accordance with RSC Terms and Conditions for Use of Self-Archived Versionsgl
dc.rights.accessRightsopen accessgl
dc.titleCopper-catalyzed protoboration of borylated dendralenes: a regio- and stereoselective access to functionalized 1,3-dienesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublicationbc42162e-5027-4c31-8ac5-2f893cb1685e
relation.isAuthorOfPublication9dca33cc-3c8d-4d1c-8644-76987c972089
relation.isAuthorOfPublication.latestForDiscoverybc42162e-5027-4c31-8ac5-2f893cb1685e

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