3-O-Benzyl-6-O-benzoyl-1,2-Oisopropilidene-5-C-nitromethyl-a-Dglucofuranose

Pampín Casal, María Begoña; Valencia Matarranz, Laura; Estévez Cabanas, Juan Carlos; Estévez Cabanas, Ramón José

doi:10.1107/S1600536808043353

3-O-Benzyl-6-O-benzoyl-1,2-Oisopropilidene-5-C-nitromethyl-a-Dglucofuranose

dc.contributor.affiliation	Universidade de Santiago de Compostela. Departamento de Química Orgánica	gl
dc.contributor.author	Pampín Casal, María Begoña
dc.contributor.author	Valencia Matarranz, Laura
dc.contributor.author	Estévez Cabanas, Juan Carlos
dc.contributor.author	Estévez Cabanas, Ramón José
dc.date.accessioned	2020-10-21T09:20:16Z
dc.date.available	2020-10-21T09:20:16Z
dc.date.issued	2008
dc.description.abstract	The title compound, C24H27NO9, is one of the epimers of the Henry reaction of 3-O-benzyl-6-O-benzoyl-2-O-isopropylidene-a-D-glucofuran-5-one with nitromethane. The conformation of the five membered rings is as expected from the precursor compound and the molecule is folded with a dihedral angle of 51.4 (2)° between the aromatic rings. One O-H...O hydrogen bond and some intramolecular and intermolecular C-H...O interactions are observed in the structure	gl
dc.description.peerreviewed	SI	gl
dc.description.sponsorship	We gratefully acknowledge the Spanish Education Ministry and the Xunta de Galicia for financial support	gl
dc.identifier.citation	Pampín, Begoña, Valencia, Laura, Estévez, Juan C., Estévez, Ramón J. (2009). 3-O-Benzyl-6-O-benzoyl-1,2-O-isopropilidene-5-C-nitromethyl-a-D-glucofuranose. "Act. Cryst". vol. 65, o332-o333	gl
dc.identifier.doi	10.1107/S1600536808043353
dc.identifier.essn	1600-5368
dc.identifier.issn	2056-9890
dc.identifier.uri	http://hdl.handle.net/10347/23390
dc.language.iso	eng	gl
dc.publisher	International Union of Crystallography	gl
dc.relation.publisherversion	https://doi.org/10.1107/S1600536808043353	gl
dc.rights	This is an open-access article distributed under the terms of the Creative Commons Attribution (CC-BY) Licence, which permits unrestricted use, distribution, and reproduction in any medium, provided the original authors and source are cited	gl
dc.rights.accessRights	open access	gl
dc.rights.uri	https://creativecommons.org/licenses/by/2.0/uk/
dc.subject	Single-crystal X-ray study	gl
dc.subject	T = 113 K	gl
dc.subject	Mean (C–C) = 0.006 A˚	gl
dc.subject	R factor = 0.047	gl
dc.subject	wR factor = 0.131	gl
dc.subject	Data-to-parameter ratio = 8.6.	gl
dc.title	3-O-Benzyl-6-O-benzoyl-1,2-Oisopropilidene-5-C-nitromethyl-a-Dglucofuranose	gl
dc.type	journal article	gl
dc.type.hasVersion	VoR	gl
dspace.entity.type	Publication
relation.isAuthorOfPublication	86b5b898-6642-4dd7-b2ee-117e2f4838ff
relation.isAuthorOfPublication	19cdf079-dc1b-48b2-8bc9-c73d3601f141
relation.isAuthorOfPublication.latestForDiscovery	86b5b898-6642-4dd7-b2ee-117e2f4838ff

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