1,7-Naphthodiyne: a new platform for the synthesis of novel, sterically congested PAHs

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URI: http://hdl.handle.net/10347/16990
ISSN: 1359-7345
E-ISSN: 1364-548X
DOI: 10.1039/C6CC01214K

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2016-03-17

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Royal Society of Chemistry
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The synthesis of an efficient precursor of the novel 1,7-naphthodiyne synthon is reported. Preliminary experiments demonstrate the usefulness of this platform for the synthesis of sterically congested polyarenes, such as helicenes and angularly fused acene derivatives. Furthermore, a novel intramolecular aryne trapping reaction is described

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Pozo, I., Cobas, A., Peña, D., Guitián, E., & Pérez, D. (2016). 1,7-Naphthodiyne: a new platform for the synthesis of novel, sterically congested PAHs. Chemical Communications, 52(32), 5534-5537. doi: 10.1039/c6cc01214k

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Financial support from the Spanish Ministry of Economy and Competitiveness (MINECO, CTQ2013-44142-P and MAT2013-46593-C6-6-P), the European Union (Project PAMS, contract no. 610446), Xunta de Galicia (GPC2014/25) and FEDER is gratefully acknowledged

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© The Royal Society of Chemistry 2016

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Centro de Investigación en Química Biolóxica e Materiais Moleculares (CiQUS)
Química Orgánica