DFT Study of the Cyclization of 1,2-divinylbenzene snd Derivatives

dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Físicagl
dc.contributor.authorCabaleiro Lago, Enrique Manuel
dc.contributor.authorPeña Gallego, María de los Ángeles
dc.contributor.authorRodríguez Otero, Jesús
dc.date.accessioned2021-08-17T11:31:46Z
dc.date.available2021-08-17T11:31:46Z
dc.date.issued2006
dc.descriptionThe 10th International Electronic Conference on Synthetic Organic Chemistry session Computational Chemistry
dc.description.abstractElectrocyclization reactions of 1,2-divinylbenzene and several related molecules were studied by performing density functional theory (DFT) calculations together with the 6-31+G* basis set. Reactants, products, and transition states for each reaction were localized and the IRC connecting reactants and products was also obtained. Magnetic properties were evaluated along the reaction path to elucidate the characteristics of the reactions studied with respect to their aromaticity and pericyclic character. Though reactions B and C seem to be borderline cases between pericyclic andpseudopericyclic behaviour, the analysis of different magnetic properties allow us to conclude that all reactions studied are pericyclicgl
dc.identifier.citationCabaleiro-Lago, E.M.; Peña-Gallego, A.; Rodríguez-Otero, J. DFT Study of the Cyclization of 1,2-divinylbenzene snd Derivatives, in Proceedings of the 10th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2006, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-10-01457gl
dc.identifier.doi10.3390/ecsoc-10-01457
dc.identifier.isbn3-906980-18-9
dc.identifier.urihttp://hdl.handle.net/10347/26818
dc.language.isoenggl
dc.publisherMDPIgl
dc.relation.ispartofseriesElectronic Conference on Synthetic Organic Chemistry;10
dc.relation.publisherversionhttps://doi.org/10.3390/ecsoc-10-01457gl
dc.rights©2007 by MDPI, Basel, Switzerland. Open Accessgl
dc.rights.accessRightsopen accessgl
dc.titleDFT Study of the Cyclization of 1,2-divinylbenzene snd Derivativesgl
dc.typebook partgl
dspace.entity.typePublication
relation.isAuthorOfPublicationcae389b7-4a38-481e-b348-4a3d4d6707fb
relation.isAuthorOfPublication41c7b009-96a5-4225-97dc-0feda160d770
relation.isAuthorOfPublication.latestForDiscoverycae389b7-4a38-481e-b348-4a3d4d6707fb

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