Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-Catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánica
dc.contributor.authorFrancos Arias, Javier
dc.contributor.authorGrande-Carmona, Francisca
dc.contributor.authorFaustino, Hélio
dc.contributor.authorIglesias Sigüenza, Francisco Javier
dc.contributor.authorDíez Martín, Elena
dc.contributor.authorAlonso García, Isaac
dc.contributor.authorFernández Fernández, Rosario Fátima
dc.contributor.authorLassaletta, José M.
dc.contributor.authorLópez García, Fernando
dc.contributor.authorMascareñas Cid, José Luis
dc.date.accessioned2019-03-27T13:45:01Z
dc.date.available2019-03-27T13:45:01Z
dc.date.issued2012
dc.description.abstractThe first highly enantioselective intermolecular (4 + 2) cycloaddition between allenes and dienes is reported. The reaction provides good yields of optically active cyclohexenes featuring diverse substitution patterns and up to three stereocenters. Key to the success of the process is the use of newly designed axially chiral N-heterocyclic carbene–gold catalystsgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipThis work was supported by the Spanish MINECO (SAF2010-20822-C02, CTQ2010-15297, CTQ2010-14974, and Consolider Ingenio 2010 CSD2007-00006), the ERDF funds, the Xunta de Galicia (INCITE09209084PR, GRC2010/12), and the Junta de Andalucía (2008/FQM-3833 and 2009/FQM-4537, predoctoral fellowship to F.G.-C). H.F. acknowledges the Fundação para a Ciência e Tecnologia (FCT, Portugal) and POPH/FSE for a Ph.D. grant (Grant SFRH/BD/60214/2009)gl
dc.identifier.citationFrancos, J., Grande-Carmona, F., Faustino, H., Iglesias-Sigüenza, J., Díez, E., Alonso, I., Fernández, R., Lassaletta, J.M., López, F. and Mascareñas, J.L. (2012). Axially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-Catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienes. J. Am. Chem. Soc., 134, 35, 14322-14325. doi: 10.1021/ja3065446gl
dc.identifier.doi10.1021/ja3065446
dc.identifier.essn1520-5126
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/10347/18480
dc.language.isoenggl
dc.publisherAmerican Chemical Societygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/SAF2010-20822-C02/ES/DISEÑO Y DESARROLLO DE PROCESOS ENANTIOSELECTIVOS CATALIZADOS POR METALES DE TRANSICION PARA LA OBTENCION DE ESTRUCTURAS POLICICLICAS BIOLOGICAMENTE RELAVANTES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC/Plan Nacional de I+D+i 2004-2007/CSD2007-00006/ES/Desarrollo de entidades organometálicas para reacciones de funcionalización selectiva en moléculas orgánicas
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/CTQ2010-15297/ES/LIGANDOS MONODENTADOS, HETEROMULTIDENTADOS Y HEMILABILES BASADOS EN CARBENOS N-HETEROCICLICOS. DEL DISEÑO RACIONAL A LAS SOLUCIONES EN CATALISIS ASIMETRICA
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/CTQ2010-14974/ES/NUEVAS ESTRATEGIAS EN CATALISIS ENANTIOSELECTIVA: SINTESIS DE LIGANDOS QUIRALES BASADOS EN HIDRAZONAS Y DESARROLLO DE REACCIONES DE FORMACION DE ENLACES C-C Y C-X
dc.relation.publisherversionhttps://doi.org/10.1021/ja3065446gl
dc.rights© 2012 American Chemical Societygl
dc.rights.accessRightsopen accessgl
dc.titleAxially Chiral Triazoloisoquinolin-3-ylidene Ligands in Gold(I)-Catalyzed Asymmetric Intermolecular (4 + 2) Cycloadditions of Allenamides and Dienesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication5ae222c9-f626-432b-aac5-da78c06ed64f
relation.isAuthorOfPublication.latestForDiscovery5ae222c9-f626-432b-aac5-da78c06ed64f

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