High-Nuclearity Metal–Organic Nanospheres: A Cd66 Ball

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánicaes_ES
dc.contributor.authorArgent, Stephen
dc.contributor.authorGreenaway, Alex
dc.contributor.authorGiménez López, María del Carmen
dc.contributor.authorLewis, William
dc.contributor.authorNowell, Harriott
dc.contributor.authorKhlobystov, Andrei N.
dc.contributor.authorBlake, Alexander
dc.contributor.authorChampness, Neil
dc.contributor.authorSchröder, Martin
dc.date.accessioned2024-02-01T08:53:40Z
dc.date.available2024-02-01T08:53:40Z
dc.date.issued2012
dc.descriptionThis document is the unedited author’s version of a submitted work that was subsequently accepted for publication in Journal of the American Chemical Society, copyright © 2011 American Chemical Society after peer review. To access the final edited and published work see https://doi.org/10.1021/ja207845ues_ES
dc.description.abstractReaction of H3L with Cd(NO3)2·4H2O in DMF at 150 °C for 3 days affords the metal–organic nanosphere [Cd66(μ3-OH)28(μ3-O)16(μ5-NO3-O,O,O′,O′,O″,O″)12(L)20(μ2-DMF)12⊂(DMF)9]. The cluster is composed of a spherical shell of 66 Cd(II) cations bridged by 28 μ3-hydroxide, 16 μ3-oxo, and five μ5-NO3– anions surrounded by a shell of 20 tripodal capping ligands (L) and 12 DMF ligands. The 66 Cd(II) cations and 12 NO3– anions form a polydeltahedron that has 78 vertices [Cd(II) or NO3–] (V), 228 edges (E), and 152 triangular faces (F), giving it an Euler characteristic (χ) of 2 (χ = V + F – E). Reaction of H3L with Cd(NO3)2·4H2O at lower temperatures or with CdCl2 affords coordination polymer frameworks instead of nanospheres.es_ES
dc.description.peerreviewedSIes_ES
dc.description.sponsorshipThis work was supported by the ERC, the EPSRC, and the University of Nottingham. M.S. gratefully acknowledges an ERC Advanced Grant and an EPSRC Programme Grant. N.R.C. gratefully acknowledges a Royal Society Leverhulme Trust Senior Research Fellowship and a Royal Society Wolfson Merit Award. We thank Victoria J. Richards for help in determining network topologies using TOPOS, (25) Dr. Sihai Yang for collecting XRPD data, and Dr. Graham Rance for assistance with DLS measurements. We also acknowledge the EPSRC National Service for Mass Spectrometry at the University of Swansea for assistance in mass spectrometric analysis and Diamond Light Source for access to Beamline I19.es_ES
dc.identifier.citationArgent, S.P., Greenaway, A., Gimenez-Lopez, M. C., Lewis, W., Nowell, H., Khlobystov, A. N., Blake, A. J., Champness, N. R., Schröder, M. (2012). High-Nuclearity Metal–Organic Nanospheres: A Cd66 Bal. "Journal of the American Chemical Society". vol. 134, 1, 55–58es_ES
dc.identifier.doi10.1021/ja207845u
dc.identifier.essn1520-5126
dc.identifier.issn0002-7863
dc.identifier.urihttp://hdl.handle.net/10347/32179
dc.language.isoenges_ES
dc.publisherAmerican Chemical Societyes_ES
dc.relation.publisherversionhttps://doi.org/10.1021/ja207845ues_ES
dc.rightsCC BY-NC-NDes_ES
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectAnionses_ES
dc.subjectCationses_ES
dc.subjectCluster chemistryes_ES
dc.subjectLigandses_ES
dc.subjectNanosphereses_ES
dc.subject.classification230321 Compuestos organometálicoses_ES
dc.titleHigh-Nuclearity Metal–Organic Nanospheres: A Cd66 Balles_ES
dc.typejournal articlees_ES
dc.type.hasVersionAMes_ES
dspace.entity.typePublication
relation.isAuthorOfPublication856421d6-de20-49ea-b0b9-e2b6b43d06ca
relation.isAuthorOfPublication.latestForDiscovery856421d6-de20-49ea-b0b9-e2b6b43d06ca

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