Straightforward Synthesis of Novel Acene-Based Aryne Precursors

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorRodríguez-Lojo, Diego
dc.contributor.authorPeña Gil, Diego
dc.contributor.authorPérez Meirás, María Dolores
dc.contributor.authorGuitián Rivera, Enrique
dc.date.accessioned2018-07-09T10:20:34Z
dc.date.available2018-07-09T10:20:34Z
dc.date.issued2015-06-11
dc.description.abstractLarge polycyclic o-(trimethylsilyl)aryl triflates are easily obtained by reaction of commercially available bisaryne precursors with cyclopentadienones. The transformation involves controlled generation of one of the aryne functionalities, trapping by Diels–Alder reaction with a dienone, and chelotropic extrusion of CO. The newly synthesized triflates are precursors of acene-based arynes, including a didehydropentacenegl
dc.description.peerreviewedSIgl
dc.description.sponsorshipFinancial support from the Spanish Ministry of Science and Competitiveness (MINECO, CTQ2013-44142-P and MAT2013-46593-C6-6-P), the European Union (Project PAMS, contract no. 610446), Xunta de Galicia (GPC2014/25), and FEDER is gratefully acknowledged. D.R.-L. thanks the Spanish Ministry of Education for the award of an FPU fellowshipgl
dc.identifier.citationPeña, D., Pérez, D., Rodríguez-Lojo, D., & Guitián, E. (2015). Straightforward Synthesis of Novel Acene-Based Aryne Precursors. Synlett, 26(11), 1633-1637. doi: 10.1055/s-0034-1381005gl
dc.identifier.doi10.1055/s-0034-1381005
dc.identifier.essn1437-2096
dc.identifier.issn0936-5214
dc.identifier.urihttp://hdl.handle.net/10347/16988
dc.language.isoenggl
dc.publisherThieme Publishinggl
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/FP7/610446
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/CTQ2013-44142-P/ES/NUEVOS RETOS EN LA QUIMICA DE ARINOS: HERRAMIENTAS SINTETICAS EN CIENCIA DE MATERIALES
dc.relation.projectIDinfo:eu-repo/grantAgreement/MINECO/Plan Estatal de Investigación Científica y Técnica y de Innovación 2013-2016/MAT2013-46593-C6-6-P/ES/HIBRIDOS COVALENTES EN SUPERFICIES
dc.relation.publisherversionhttps://doi.org/10.1055/s-0034-1381005gl
dc.rights© Georg Thieme Verlag Stuttgart · New Yorkgl
dc.rights.accessRightsopen accessgl
dc.subjectArynesgl
dc.subjectPolycyclic aromatic hydrocarbonsgl
dc.subjectAcenesgl
dc.subjectDiels–Alder reactiongl
dc.subjectCycloadditionsgl
dc.titleStraightforward Synthesis of Novel Acene-Based Aryne Precursorsgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
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relation.isAuthorOfPublication9234e3fc-1c91-4a8d-b859-82185be7325d
relation.isAuthorOfPublicatione5edf167-dde8-4058-a344-ca0b15f93b2c
relation.isAuthorOfPublication.latestForDiscovery22b9fb25-7d2c-4d33-a599-e1c0d0b7de71

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