Cobalt-Catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dienes

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Moleculareses_ES
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicaes_ES
dc.contributor.authorDa Concepción, Eduardo
dc.contributor.authorFernández, Israel
dc.contributor.authorMascareñas Cid, José Luis
dc.contributor.authorLópez García, Fernando
dc.date.accessioned2024-02-16T12:17:58Z
dc.date.available2024-02-16T12:17:58Z
dc.date.issued2023
dc.description.abstractLow-valent cobalt complexes equipped with phosphorous type of ligands can promote the intramolecular (3+2) cycloaddition of alkylidenecyclopropanes (ACPs) with alkenes and with allenes. Dienes can also be used as partners, but they afford seven-membered cycloadducts. The reactions are fully diastereoselective and, in some cases, we also observed moderate enantioselectivities, especially when using chiral phosphite ligands.es_ES
dc.description.peerreviewedSIes_ES
dc.description.sponsorshipThis work received financial support from Spanish grants (Grants PID2020-118579GB−I00 and PID2019-108624RB−I00 funded by MCIN/AEI/10.13039/501100011033, ORFEO-CINQA network RED2022-134287-T), the Consellería de Cultura, Educación e Ordenación Universitaria (Grant ED431C 2021/25 and Grant ED431G 2019/03: Centro Singular de Investigación de Galicia accreditation 2019–2022, and predoctoral grant to EdC) and the European Union (European Regional Development Fund-ERDF corresponding to the multiannual financial framework 2014–2020).es_ES
dc.identifier.citationAdvanced Synthesis & Catalysis (ASC).es_ES
dc.identifier.doi10.1002/adsc.202301040
dc.identifier.essn1615-4169
dc.identifier.urihttp://hdl.handle.net/10347/32851
dc.language.isoenges_ES
dc.publisherWileyes_ES
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2020-118579GB-I00/ES/METODOS SINTETICOS ENANTIOSELECTIVOS BASADOS EN CATALISIS CON METALES DE TRANSICION Y APLICACIONES DE LOS MISMOS/es_ES
dc.relation.publisherversionhttps://doi.org/10.1002/adsc.202301040es_ES
dc.rights© 2023 The Authors. Advanced Synthesis & Catalysis published by Wiley-VCHGmbH.This is an open access article under the terms of the Creative Commons Attribution-NonCommercial-NoDerivs Licensees_ES
dc.rightsAttribution-NonCommercial-NoDerivatives 4.0 Internacional
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectCobaltes_ES
dc.subjectAlkylidenecyclopropanees_ES
dc.subjectCycloadditiones_ES
dc.subjectAllenees_ES
dc.subjectDienees_ES
dc.titleCobalt-Catalyzed Intramolecular Cycloadditions of Alkenylidenecyclopropanes with Alkenes and Dieneses_ES
dc.typejournal articlees_ES
dc.type.hasVersionVoRes_ES
dspace.entity.typePublication
relation.isAuthorOfPublication5ae222c9-f626-432b-aac5-da78c06ed64f
relation.isAuthorOfPublication.latestForDiscovery5ae222c9-f626-432b-aac5-da78c06ed64f

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