An on-surface Diels–Alder reaction

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorCastro Esteban, Jesús
dc.contributor.authorAlbrecht, Florian
dc.contributor.authorFatayer, Shadi
dc.contributor.authorPérez Meirás, María Dolores
dc.contributor.authorGross, Leo
dc.contributor.authorPeña Gil, Diego
dc.date.accessioned2022-08-11T10:56:08Z
dc.date.available2022-08-11T10:56:08Z
dc.date.issued2021
dc.description.abstractThe Diels–Alder reaction is one of the most popular reactions in organic chemistry. However, its use in the field of on-surface synthesis is hampered by the spatial restrictions of this cycloaddition reaction. Herein we selected a cyclic strained triyne to demonstrate an on-surface hexadehydro-Diels–Alder reaction in a single molecule. The reaction was studied in detail by means of atomic force microscopy (AFM) with CO-functionalized tips. Our results pave the way to use this iconic pericyclic reaction for on-surface synthesis, introducing the concept of atom economy in the fieldgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipWe thank Rolf Allenspach and Enrique Guitián for discussions. We thank the European Union (Project SPRING, contract no. 863098), the ERC grant AMSEL (682144), the Spanish Agencia Estatal de Investigación (PID2019-107338RB-C62, PID2019-110037GB-I00 and PCI2019-111933-2), Xunta de Galicia (Centro de Investigación de Galicia accreditation 2019–2022, ED431G 2019/03) and the European Regional Development Fund-ERDF for financial supportgl
dc.identifier.citationAngew. Chem. Int. Ed. 2021, 60, 26346 – 26350. https://doi.org/10.1002/anie.202110311gl
dc.identifier.doi10.1002/anie.202110311
dc.identifier.essn1521-3773
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/10347/29052
dc.language.isoenggl
dc.publisherWileygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PCI2019-111933-2/SINTESIS EN DISOLUCION PARA LA INTEGRACION DEL GRAFENO NANOPOROSO MULTIFUNCIONAL EN BIOSENSORES NANOFOTONICOS
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/863098gl
dc.relation.projectIDinfo:eu-repo/grantAgreement/EC/H2020/682144gl
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-107338RB-C62/ES/SINTESIS EN DISOLUCION PARA SISTEMAS MOLECULARES FUNCIONALESgl
dc.relation.projectIDinfo:eu-repo/grantAgreement/AEI/Plan Estatal de Investigación Científica y Técnica y de Innovación 2017-2020/PID2019-110037GB-I00/LEGO MOLECULAR BASADO EN ARINOS: APLICACION A LA SINTESIS DE HIDROCARBUROS POLICICLICOS CONJUGADOS Y MATERIALES FUNCIONALESgl
dc.relation.publisherversionhttps://doi.org/10.1002/anie.202110311gl
dc.rights©2021 The Authors. Angewandte Chemie International Edition published by Wiley-VCH GmbH. This is an open access article under the terms of the Creative Commons Attribution Non-Commercial NoDerivs License, which permits use and distribution in any medium, provided the original work is properly cited, the use is noncommercial and no modifications or adaptations are madegl
dc.rights.accessRightsopen accessgl
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectBond-resolved AFMgl
dc.subjectCycloadditiongl
dc.subjectDiels–Alder reactiongl
dc.subjectOn-surface synthesisgl
dc.subjectPolycyclic aromatic hydrocarbonsgl
dc.titleAn on-surface Diels–Alder reactiongl
dc.typejournal articlegl
dc.type.hasVersionVoRgl
dspace.entity.typePublication
relation.isAuthorOfPublication6b74af8e-3008-403a-9f6c-599845be3031
relation.isAuthorOfPublication9234e3fc-1c91-4a8d-b859-82185be7325d
relation.isAuthorOfPublication22b9fb25-7d2c-4d33-a599-e1c0d0b7de71
relation.isAuthorOfPublication.latestForDiscovery22b9fb25-7d2c-4d33-a599-e1c0d0b7de71

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