Functionalized thiosemicarbazone ligands and their complexes
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Abstract
The purpose of this work is the design, synthesis and characterization of thiosemicarbazone ligands bearing a phenyl boronic acid functionality. The main interest is the synthesis of organopalladium compounds with the boronic acid included within the corresponding molecule. These could lead to further modification of the properties of the organometallic species applicable to the Suzuki-Miyaura reaction.
The ligands were prepared by reaction of acetylphenylboronic acid with several thiosemicarbazides. The compounds were characterized by IR, 1H and 31P NMR spectroscopy
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The 20th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis
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Reigosa, F., Lucio-Martínez, F., Fernández-Figueiras, A., Munín, P., Vila, J.M., Pereira, M.T. & Frieiro, P. (2016). Functionalized thiosemicarbazone ligands and their complexes. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin. (Ed.), Proceedings ECSOC-20: The 20Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2016. MDPI. doi: 10.3390/ecsoc-20-a041
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https://doi.org/10.3390/ecsoc-20-a041Sponsors
We wish to thank the financial support received from the Xunta de Galicia (Galicia, Spain) under the Grupos de Referencia Competitiva Programme Projects GRC2015/009.
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© 2016 by MDPI, Basel, Switzerland. Open Access








