Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorCambeiro Cambeiro, Fermín
dc.contributor.authorLópez Estévez, Susana
dc.contributor.authorVarela Carrete, Jesús Ángel
dc.contributor.authorSaá Rodríguez, Carlos
dc.date.accessioned2020-10-05T06:31:27Z
dc.date.available2020-10-05T06:31:27Z
dc.date.issued2011
dc.descriptionNOTICE: This is the peer reviewed version of the following article: Cambeiro, F., López, S., Varela, J. A., Saá, C. (2017). Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds. Angew. Chem. Int. Ed. 2012, 51, 3, 723-727. [doi: 10.1002/anie.201107344]. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archivinggl
dc.description.abstractA novel tandem Ru-catalyzed carbene addition to terminal alkynes/insertion of Csp3–H bonds in alkynyl acetals, ethers and amines has been accomplished under mild conditions. This cascade provides an efficient approach to form complex spiro and fused bicyclic structures in 1,5- and 1,6-hydride shift/cyclization sequences from vinylcarbene Ru intermediates.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipWe thank the MICINN [Projects CTQ2008-06557, CTQ2011-28258, Consolider Ingenio 2010 (CSD2007-00006)] and Xunta de Galicia (2007/XA084 and CN2011/054) for financial support. F. C. thanks the Xunta de Galicia and MICINN for a predoctoral grantgl
dc.identifier.citationCambeiro, F., López, S., Varela, J. A., Saá, C. (2012). Cyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bonds. Angew. Chem. Int. Ed., 51, 3, 723-727gl
dc.identifier.doi10.1002/anie.201107344
dc.identifier.essn1521-3773
dc.identifier.issn1433-7851
dc.identifier.urihttp://hdl.handle.net/10347/23339
dc.language.isoenggl
dc.publisherWileygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC/Plan Nacional de I+D+i 2004-2007/CSD2007-00006/ES/Desarrollo de entidades organometálicas para reacciones de funcionalización selectiva en moléculas orgánicas
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/CTQ2011-28258/ES/CATALISIS ORGANOMETALICA: FUNCIONALIZACION DE ENLACES C-H
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/CTQ2008-06557/ES/NUEVAS CICLACIONES CATALIZADAS POR METALES DE TRANSICION. APLICACIONES DE LA CATALISIS ORGANOMETALICA A LA SINTESIS DE POLIACETILENOS CON ACTIVIDAD ANTITUMORAL
dc.relation.publisherversionhttps://dx.doi.org/10.1002/anie.201107344gl
dc.rightsCopyright © 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for self-archivinggl
dc.rights.accessRightsopen accessgl
dc.subjectAlkynyl derivativesgl
dc.subjectCarbenesgl
dc.subjectCyclizationgl
dc.subjectRutheniumgl
dc.subjectSpiro compoundsgl
dc.titleCyclization by Catalytic Ruthenium Carbene Insertion into Csp3-H Bondsgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication9fa39cb0-6565-4473-a88f-10574caa68a1
relation.isAuthorOfPublicatione9be05f9-b5a3-405c-aaf6-4e32700dd21d
relation.isAuthorOfPublication2c024eb2-7698-4785-bd0c-518f70068330
relation.isAuthorOfPublication.latestForDiscovery9fa39cb0-6565-4473-a88f-10574caa68a1

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