Rh(III)-Catalyzed Tandem C-H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorCajaraville Leiro, Ana
dc.contributor.authorLópez Estévez, Susana
dc.contributor.authorVarela Carrete, Jesús Ángel
dc.contributor.authorSaá Rodríguez, Carlos
dc.date.accessioned2020-10-05T06:37:06Z
dc.date.available2020-10-05T06:37:06Z
dc.date.issued2013
dc.descriptionNOTICE: This is the peer reviewed version of the following article: Cajaraville, A., López, S., Varela, J. A., Saá, C. (2013). Rh(III)-Catalyzed Tandem C-H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles. Org. Lett., 15, 17, 4576-4579. [doi: 10.1021/ol402125t]. This article may be used for non-commercial purposes in accordance with American Chemical Society Terms and Conditions for self-archivinggl
dc.description.abstractRhIII-catalyzed tandem C-H allylation and oxidative cyclization of anilides with allyl carbonates in the presence of a slight excess of AgSbF6 salt and Cu(OAc)2 as oxidant affords easy, economical access to important bioactive 2-methylindoles. The new reaction supports a wide range of functional groups on the anilide substrate. A possible mechanism is proposed as a basis for its rational further development.gl
dc.description.peerreviewedSIgl
dc.description.sponsorshipThis work was supported by MICINN [projects CTQ2011-28258 and Consolider Ingenio 2010 (CSD2007-00006)] and Xunta de Galicia (projects CN2011/054 and EM 2012/051). We thank M. J. Cotón for preliminary experiments. A.C. thanks Ministerio de Ciencia e Innovación for a FPI predoctoral fellowshipgl
dc.identifier.citationCajaraville, A., López, S., Varela, J. A., Saá, C. (2013). Rh(III)-Catalyzed Tandem C-H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indoles. Org. Lett., 15, 17, 4576-4579gl
dc.identifier.doi10.1021/ol402125t
dc.identifier.essn1523-7052
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10347/23342
dc.language.isoenggl
dc.publisherAmerican Chemical Societygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/MEC/Plan Nacional de I+D+i 2004-2007/CSD2007-00006/ES/Desarrollo de entidades organometálicas para reacciones de funcionalización selectiva en moléculas orgánicas
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/CTQ2011-28258/ES/CATALISIS ORGANOMETALICA: FUNCIONALIZACION DE ENLACES C-H
dc.relation.publisherversionhttps://doi.org/10.1021/ol402125tgl
dc.rightsCopyright © 2013 American Chemical Society. This article may be used for non-commercial purposes in accordance with American Chemical Society Terms and Conditions for self-archivinggl
dc.rights.accessRightsopen accessgl
dc.subjectCyclizationgl
dc.subjectIndolesgl
dc.subjectInorganic carbon compoundsgl
dc.subjectOxidative cyclizationgl
dc.subjectAllyl groupgl
dc.titleRh(III)-Catalyzed Tandem C-H Allylation and Oxidative Cyclization of Anilides: A New Entry to Indolesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
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relation.isAuthorOfPublicatione9be05f9-b5a3-405c-aaf6-4e32700dd21d
relation.isAuthorOfPublication2c024eb2-7698-4785-bd0c-518f70068330
relation.isAuthorOfPublication.latestForDiscovery9fa39cb0-6565-4473-a88f-10574caa68a1

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