Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánicaes_ES
dc.contributor.authorCoronado, Eugenio
dc.contributor.authorGalán Mascarós, José R.
dc.contributor.authorGiménez López, María del Carmen
dc.contributor.authorAlmeida, Manuel
dc.contributor.authorWaerenborgh, João Carlos
dc.date.accessioned2024-02-05T09:45:02Z
dc.date.available2024-02-05T09:45:02Z
dc.date.issued2006
dc.description.abstractWe present the synthesis and structural characterization of the salt [Fe(bpp)2][MnCr(ox)3]2 · bpp · CH3OH. It crystallizes in the monoclinic space group. This material contains an anionic [MnCr(ox)3]− 3D 10-gon ferromagnetic network, that orders below 3.0 K. The channels created by this architecture are filled by the spin crossover cations [Fe(bpp)2]2+ (bpp = 2,6(bispyrazol-3-yl)pyridine), free ligand and solvent molecules. No spin transition has been observed at ambient pressure.es_ES
dc.description.peerreviewedSIes_ES
dc.description.sponsorshipThis work was supported by the European Union (Network of Excellence: MAGMANET). Financial support from the Ministerio de Educación y Ciencia (Projects MAT2004-3849 and BQU2002-01091), and from the Generalitat Valenciana (GV04A/77) is also acknowledged.es_ES
dc.identifier.citationCoronado, E., Galán Mascarós, J.R., Giménez-López, M.C., Almeida, M., Waerenborgh, J.C. (2006). Spin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnets. "Polyhedron". Vol.26, n. 9–11, 1838-1844es_ES
dc.identifier.doi10.1016/j.poly.2006.09.064
dc.identifier.essn1873-3719
dc.identifier.issn0277-5387
dc.identifier.urihttp://hdl.handle.net/10347/32319
dc.language.isoenges_ES
dc.publisherElsevieres_ES
dc.relation.publisherversionhttps://doi.org/10.1016/j.poly.2006.09.064es_ES
dc.rightsCC BY-NC-ND 4.0es_ES
dc.rights.accessRightsopen accesses_ES
dc.rights.urihttp://creativecommons.org/licenses/by-nc-nd/4.0/
dc.subjectCoordination chemistryes_ES
dc.subjectMolecular materialses_ES
dc.subjectSpin crossoveres_ES
dc.subjectMagnetic propertieses_ES
dc.subjectMössbauer spectroscopyes_ES
dc.subject.classification230307 Compuestos de coordinaciónes_ES
dc.subject.classification220208 Magnetismoes_ES
dc.titleSpin crossover FeII complexes as templates for bimetallic oxalate-based 3D magnetses_ES
dc.typejournal articlees_ES
dc.type.hasVersionAMes_ES
dspace.entity.typePublication
relation.isAuthorOfPublication856421d6-de20-49ea-b0b9-e2b6b43d06ca
relation.isAuthorOfPublication.latestForDiscovery856421d6-de20-49ea-b0b9-e2b6b43d06ca

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