Synthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppm

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánicagl
dc.contributor.authorRúa Sueiro, Marcos
dc.contributor.authorMunín Cruz, Paula
dc.contributor.authorReigosa Chamorro, Francisco
dc.contributor.authorVila Abad, José Manuel
dc.contributor.authorOrtigueira Amor, Juan Manuel
dc.date.accessioned2021-02-15T13:56:10Z
dc.date.available2021-02-15T13:56:10Z
dc.date.issued2021
dc.description.abstractCyclometallated compounds have been extensively studied, in particular those with palladium and platinum. This is because of their possible applications in medicinal chemistry, as anticancer or antimicrobial agents; in some cases, with similar results as cisplatin, carboplatin or oxaliplatin. What is also remarkable is their use as homogeneous catalysts, for example, in cross coupling reactions such as Suzuki–Miyaura or Mizoroki–Heck. Herein, we report the synthesis of different thiosemicarbazone ligands, which will be reacted with a palladium or platinum salt, to give the corresponding cyclometallated compounds; in addition, their reactivity with bis(diphenylphosphino)methane (dppm) will be studied. Characterization has been carried out by elemental analysis, IR spectroscopy, 1H and 31P NMR spectroscopy. Additionally, 1c has been studied by X-ray diffractiongl
dc.description.peerreviewedSIgl
dc.description.sponsorshipFrancisco Reigosa wants to thank the Spanish Government (AEI) for their financial support through an FPU grant (number 13/05014). The authors thank funding from Xunta de Galicia (Galicia, Spain) under the Grupos de Referencia program (GRC 2019/014)gl
dc.identifier.citationProceedings 2020, 62(1), 13; https://doi.org/10.3390/proceedings2020062013gl
dc.identifier.doi10.3390/proceedings2020062013
dc.identifier.essn2504-3900
dc.identifier.urihttp://hdl.handle.net/10347/24466
dc.language.isoenggl
dc.publisherMDPIgl
dc.relation.publisherversionhttps://doi.org/10.3390/proceedings2020062013gl
dc.rights© 2021 by the authors. Licensee MDPI, Basel, Switzerland. This article is an open access article distributed under the terms and conditions of the Creative Commons Attribution (CC BY) license (http://creativecommons.org/licenses/by/4.0/)gl
dc.rightsAtribución 4.0 Internacional
dc.rights.accessRightsopen accessgl
dc.rights.urihttp://creativecommons.org/licenses/by/4.0/
dc.subjectCyclometallationgl
dc.subjectThiosemicarbazonegl
dc.subjectPalladiumgl
dc.subjectPlatinumgl
dc.subjectX-ray diffractiongl
dc.titleSynthesis and X-ray Diffraction Study of thiosemicarbazone Palladacycles with dppmgl
dc.typejournal articlegl
dc.type.hasVersionVoRgl
dspace.entity.typePublication
relation.isAuthorOfPublication87debb6c-6b40-4195-a8fe-bb89e934ea64
relation.isAuthorOfPublicationbfde9065-7b4d-487d-925b-4f3b42acaff8
relation.isAuthorOfPublication.latestForDiscovery87debb6c-6b40-4195-a8fe-bb89e934ea64

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