Total Hydrolysis of a New Imidazolidine Induced by ZnII

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URI: http://hdl.handle.net/10347/25956
ISBN: 978-3-906980-55-3
DOI: 10.3390/ecsoc-18-a026

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2015

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Abstract

2,2´-(2-(2-hydroxyphenyl)imidazolidin-1,3-diyl)diethanol(H3L) was obtained by condensation between 2-hydroxybenzaldehyde and N,N'-bis(2-hydroxyethyl)ethylenediamine. Its potential ability as NNOOO donor towards ZnII was tested. This study shows that zinc(II) mediates the fast hydrolysis of H3L, yielding the free aldehyde and amine. This latter was crystallographically characterised, showing a supramolecular 1D architecture based on hydrogen bond interactions

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The 18th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

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Imidazolidine| Hydrolysis| Zinc| 1D ladder

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Fondo, M., Doejo, J., García-Deibe, A.M., Sanmartín-Matalobos, J. & González-Bello, C. (2015). Total Hydrolysis of a New Imidazolidine Induced by ZnII. In J.A. Seijas, M.P. Vázquez Tato & S.K. Lin, Proceedings ECSOC-18: The 18Th International Electronic Conference On Synthetic Organic Chemistry: November 1-30, 2014. MDPI. doi: 10.3390/ecsoc-18-a026

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© 2015 by MDPI, Basel, Switzerland. Open Access

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Química Inorgánica
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