Towards taxane analogues synthesis by dienyne ring closing metathesis

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URI: http://hdl.handle.net/10347/17005
E-ISSN: 2052-4129
DOI: 10.1039/C6QO00321D

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2016-10-01

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Royal Society of Chemistry
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Herein we report the facile construction of taxadiene analogues by ring closing metathesis of dienynes built on a cyclohexenone with a natural configuration at C1 and its further transformation to incorporate most of the key functional groups of taxol

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Taxane| Ring closing metathesis

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Pérez-Estrada, S.,Sayar, N. & Granja, J. (2017). Towards taxane analogues synthesis by dienyne ring closing metathesis . Org. Chem. Front., 2016,3, 1331-1336 . http://dx.doi.org/10.1039/C6QO00321D

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This work was supported by the Spanish Ministry of Economy and Competitivity (Mineco) and the ERDF (CTQ2010‐15725, CTQ2013‐43264‐R and CTQ2014‐51912‐REDC), and by the Xunta de Galicia and the ERDF (GPC2013‐039, EM2012/117 and EM2014/011). N. S. thanks Mineco for his FPU contract and S. P.‐E. to the CONACYT for his fellowship (No. 162219). We also thank ORFEO‐CINCA network

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© The Royal Society of Chemistry 2016

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Centro de Investigación en Química Biolóxica e Materiais Moleculares (CiQUS)
Química Orgánica