A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure

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ISSN: 1359-7345
E-ISSN: 1364-548X

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Royal Society of Chemistry
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The synthesis of a [60]fullerene-benzyne building block and its further chemical cycloaddition reaction with graphene has resulted in a new all-carbon hybrid material which has been characterized by TGA, FTIR and Raman spectroscopies, XPS as well as AFM and TEM. Based on computational studies, the formation of both [2+2] and [4+2] cycloadducts on the graphene surface is feasible

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García, D., Rodríguez-Pérez, L., Herranz, M., Peña, D., Guitián, E., & Bailey, S. et al. (2016). A C60-aryne building block: synthesis of a hybrid all-carbon nanostructure. Chemical Communications, 52(40), 6677-6680. doi: 10.1039/c5cc10462a

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Financial support from the European Research Council (ERC-320441-Chiralcarbon), the European Commission (EC) FP7 ITN ‘‘MOLESCO’’ Project No. 606728 and FP7 ICT-2013-FET ‘‘PAMS’’ Project No. 610446, the UK EPSRC (Project No. EP/N017188/1 (QuEEN)), the Ministerio de Economía y Competitividad (MINECO) of Spain (Projects CTQ2013-44142-P, MAT2013-46593-C6-6-P, CTQ2014-52045-R and CTQ2015-71936-REDT), the CAM (PHOTOCARBON project S2013/MIT-2841) and FEDER is acknowledged

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© The Royal Society of Chemistry 2016