Stereoselective Formation of Chiral Metallopeptides

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Inorgánicagl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorRama, Gustavo
dc.contributor.authorArdá, Ana
dc.contributor.authorMaréchal, Jean-Didier
dc.contributor.authorGamba, Ilaria
dc.contributor.authorIshida, Hitoshi
dc.contributor.authorJiménez Barbero, Jesús
dc.contributor.authorVázquez Sentís, Marco Eugenio
dc.contributor.authorVázquez López, Miguel
dc.date.accessioned2018-07-10T12:59:39Z
dc.date.available2018-07-10T12:59:39Z
dc.date.issued2012-05-03
dc.descriptionThis is the peer reviewed version of the following article: Rama, G., Ardá, A., Maréchal, J., Gamba, I., Ishida, H., Jiménez‐Barbero, J., Vázquez, M. E. and Vázquez López, M. (2012), Stereoselective Formation of Chiral Metallopeptides. Chem. Eur. J., 18: 7030-7035, which has been published in final form at https://doi.org/10.1002/chem.201201036. This article may be used for non-commercial purposes in accordance with Wiley Terms and Conditions for Use of Self-Archived Versionsgl
dc.description.abstractPlaying into our hands: The achiral bipyridine amino acid fluorenylmethyloxycarbonyl 5‐amino‐3‐oxapentanoic acid (Fmoc‐O1PenBpy‐OH) has been used for the solid‐phase synthesis of metallopeptides. Circular dichroism, molecular modeling, and NMR spectroscopic studies show that the chirality of the resulting metal complexes in aqueous solution is determined, and can thus be controlled, by the stereochemistry of one proline residue in the loop between the two coordinating O1PenBpy residuesgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipConsolider Ingenio. Grant Number: CSD2007‐00006 Xunta de Galicia. Grant Numbers: INCITE09 209 084PR, GRC2010/12, PGIDIT08CSA‐047209PR PRESTO Program of JST Grant‐in‐Aid for Scientific Research (C) from the Ministry of Education, Culture, Sports, Science, and Technology. Grant Number: 21550163 International Iberian Nanotechnology Laboratory (INL)gl
dc.identifier.citationRama, G., Ardá, A. , Maréchal, J., Gamba, I., Ishida, H., Jiménez‐Barbero, J., Vázquez, M. E. and Vázquez López, M. (2012), Stereoselective Formation of Chiral Metallopeptides. Chem. Eur. J., 18: 7030-7035. doi:10.1002/chem.201201036gl
dc.identifier.doi10.1002/chem.201201036
dc.identifier.essn1521-3765
dc.identifier.urihttp://hdl.handle.net/10347/17008
dc.language.isoenggl
dc.publisherWileygl
dc.relation.publisherversionhttps://doi.org/10.1002/chem.201201036gl
dc.rights© 2012 WILEY‐VCH Verlag GmbH & Co. KGaA, Weinheim. This article may be used for non-commercial purposes in accordance with Wiley-VCH Terms and Conditions for Self-Archivinggl
dc.rights.accessRightsopen accessgl
dc.subjectChiralitygl
dc.subjectLigand effectsgl
dc.subjectMetallopeptidesgl
dc.subjectMolecular modelinggl
dc.subjectNMR spectroscopygl
dc.subjectPeptidesgl
dc.titleStereoselective Formation of Chiral Metallopeptidesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublication34f1e1e8-411b-4b42-a25c-253481d3abef
relation.isAuthorOfPublication49ee56a2-7094-407b-8108-b55c5968f241
relation.isAuthorOfPublication.latestForDiscovery34f1e1e8-411b-4b42-a25c-253481d3abef

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