Ethyl 2-(Diisopropoxyphosphoryl)-2H-Azirine-3-Carboxylate: Reactions with Activated 1,3-Butadienes

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URI: http://hdl.handle.net/10347/26844
ISBN: 3-906980-20-0
DOI: 10.3390/ecsoc-12-01222

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2008

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MDPI
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Abstract

Ethyl 2-(diisopropoxyphosphoryl)-2H-azirine-3-carboxylate was generated “in situ” and reacted with a number of 1,3-butadienes. Cycloadducts, or in one case an ensuing rearranged product, were isolated with moderate to good yields

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The 12th International Electronic Conference on Synthetic Organic Chemistry session General Organic Synthesis

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2H-Azirines| Aza-Diels-Alder cycloaddition| Dienophiles| Phosphonate derivative compounds

Bibliographic citation

Alves, M.; Lemos, A.; Rodriguez-Borges, J.E.; García-Mera, X. Ethyl 2-(Diisopropoxyphosphoryl)-2H-Azirine-3-Carboxylate: Reactions with Activated 1,3-Butadienes, in Proceedings of the 12th International Electronic Conference on Synthetic Organic Chemistry, 1–30 November 2008, MDPI: Basel, Switzerland, doi:10.3390/ecsoc-12-01222

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The authors thank Fundação para a Ciência e Tecnologia, CIQA-Centro de Investigação em Química do Algarve and Xunta de Galicia for financial support under project 07CSA008203PR

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© 2008 The author(s). Published by MDPI, Basel, Switzerland. Open Access

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Química Orgánica