A Two-Step, Stereoselective Synthesis of Nine- and Ten-Membered Carbocycles from Phthalates

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dc.contributor.affiliationUniversidade de Santiago de Compostela. Centro de Investigación en Química Biolóxica e Materiais Molecularesgl
dc.contributor.affiliationUniversidade de Santiago de Compostela. Departamento de Química Orgánicagl
dc.contributor.authorPrado, Gustavo
dc.contributor.authorVeiga, Alberte X.
dc.contributor.authorFernández-Nieto, Fernando
dc.contributor.authorPaleo Pillado, María Rita
dc.contributor.authorSardina López, Francisco Javier
dc.date.accessioned2018-07-09T08:58:22Z
dc.date.available2018-07-09T08:58:22Z
dc.date.issued2015
dc.description.abstractA two-step, stereoselective procedure for the synthesis of nine- and ten-membered carbocycles from readily available phthalates is described. A variety of dialkyl phthalates have been transformed into [6,n]-fused bicyclo systems (n = 5, 6, 7) by a dearomatization/cyclization process and then converted into cyclonona- and cyclodecadienes through a bond cleavage reaction, whereby both processes are promoted by alkaline metals in THFgl
dc.description.peerreviewedSIgl
dc.description.sponsorshipThis work was supported by the Spanish MINECO (CTQ2011-22436), and the Xunta de Galicia (GRC2014/029)gl
dc.identifier.citationPrado, G., Veiga, A., Fernández-Nieto, F., Paleo, M., & Sardina, F. (2015). A Two-Step, Stereoselective Synthesis of Nine- and Ten-Membered Carbocycles from Phthalates. Org. Lett., 17(9), 2054-2057. doi: 10.1021/acs.orglett.5b00552gl
dc.identifier.doi10.1021/acs.orglett.5b00552
dc.identifier.essn1523-7052
dc.identifier.issn1523-7060
dc.identifier.urihttp://hdl.handle.net/10347/16987
dc.language.isoenggl
dc.publisherAmerican Chemical Societygl
dc.relation.projectIDinfo:eu-repo/grantAgreement/MICINN/Plan Nacional de I+D+i 2008-2011/CTQ2011-22436/ES/REACTIVIDAD QUIMICA EN SISTEMAS COLOIDALES DERIVADOS DE AGREGADOS SUPRAMOLECULARES
dc.relation.publisherversionhttps://doi.org/10.1021/acs.orglett.5b00552gl
dc.rights© 2015 American Chemical Societygl
dc.rights.accessRightsopen accessgl
dc.titleA Two-Step, Stereoselective Synthesis of Nine- and Ten-Membered Carbocycles from Phthalatesgl
dc.typejournal articlegl
dc.type.hasVersionAMgl
dspace.entity.typePublication
relation.isAuthorOfPublicationff51de10-efdc-4fd3-9fab-8f2ab82f663b
relation.isAuthorOfPublicationd2ead1ad-132f-4d2d-9aff-5d8afd8237c9
relation.isAuthorOfPublication.latestForDiscoveryff51de10-efdc-4fd3-9fab-8f2ab82f663b

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